503622-15-9

Upstream product

• 598-40-3 ethyl iodoacetate 
• 527698-54-0 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenol 
• 224191-80-4 4-triallylmethylphenol 

Downstream Products

• 503622-16-0 4-[4-{[4-(1,1-diallyl-but-3-enyl)-phenoxymethyl]-dimethyl-silanyl}-1,1-bis-(3-{[4-(1,1-diallyl-but-3-enyl)-phenoxymethyl]-dimethyl-silanyl}-propyl)-butyl]-phenol 

Relevant academic research and scientific papers

Convergent dendron approach using a phenol triallyl building block: Synthesis of a phenol dendron containing 27 allyl termini

A successful convergent dendron synthesis is achieved using a phenol triallyl (AB3) building block by a sequence of reactions consisting of hydrosilylation-phenol protection. The key feature is the hydrosilylation using dimethylchloromethylsilane that avoids the side dehydrohalogenation previously found with linear branches containing β-hydrogens. The advantage of the AB3 building block is the multiplication of the dendron branches by three at each generation, which allows the synthesis of the second-generation 27-allyl phenol dendron.