propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester

Base Information

• Chemical Name: propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester
• CAS No.: 503622-15-9
• Molecular Formula: C₂₈H₅₁I₃O₂Si₃
• Molecular Weight: 884.682
• Mol file: 503622-15-9.mol

Synonyms:propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester

Chemical Property of propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester

There total 2 articles about propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

ethyl iodoacetate (598-40-3) + 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenol (527698-54-0) → propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester (503622-15-9)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 16h;

DOI:10.1039/b210358n

Reference yield:

4-triallylmethylphenol (224191-80-4) → propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester (503622-15-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 91 percent / diethyl ether / 48 h / 20 °C

2: 99 percent / NaI / butan-2-one / 24 h / 80 °C

3: 91 percent / NEt(iPr)2 / CH₂Cl₂ / 16 h / 20 °C

With N-ethyl-N,N-diisopropylamine; sodium iodide; In diethyl ether; dichloromethane; butanone;

DOI:10.1039/b210358n

Reference yield: 68.0%

4-triallylmethylphenol (224191-80-4) + propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester (503622-15-9) → 4-[4-{[4-(1,1-diallyl-but-3-enyl)-phenoxymethyl]-dimethyl-silanyl}-1,1-bis-(3-{[4-(1,1-diallyl-but-3-enyl)-phenoxymethyl]-dimethyl-silanyl}-propyl)-butyl]-phenol (503622-16-0)

Guidance literature:

4-triallylmethylphenol; propionic acid 4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenyl ester; With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 48h;

With water; potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 24h; Further stages.;

DOI:10.1039/b210358n

upstream raw materials:

ethyl iodoacetate

4-{4-(iodomethyl-dimethyl-silanyl)-1,1-bis-[3-(iodomethyl-dimethyl-silanyl)-propyl]-butyl}-phenol

4-triallylmethylphenol

Downstream raw materials:

4-[4-{[4-(1,1-diallyl-but-3-enyl)-phenoxymethyl]-dimethyl-silanyl}-1,1-bis-(3-{[4-(1,1-diallyl-but-3-enyl)-phenoxymethyl]-dimethyl-silanyl}-propyl)-butyl]-phenol