50423-48-8

Upstream product

• 50423-49-9 1,2-bis(iodomethyl)benzene 
• 886050-81-3 1,2-bis(3-(trimethylsilyl)prop-2-yn-1-yl)benzene 
• 91-13-4 α,α'-dibromo-o-xylene 

Downstream Products

• 1072066-45-5 9,10-dihydro-2,3-diphenylanthracene 
• 1072066-58-0 5,10-dihydro-3-phenylbenzo[g]isoquinoline 
• 78239-34-6 1,1-difluoro-1H-cyclopropanthracene 
• 287-03-6 1H-cyclopropaanthracene 

Relevant academic research and scientific papers

Ligand-Field Energy Splitting in Lanthanide-Based Single-Molecule Magnets by NMR Spectroscopy

A method for the experimental determination of ligand-field (LF) energy splitting in mononuclear lanthanide complexes, based purely on variable-temperature NMR spectroscopy, was developed. The application of this method in an isostructural series of anion

Preparation of Structurally and Electronically Diverse N → B-Ladder Boranes by [2 + 2 + 2] Cycloaddition

We report the synthesis of a series of eight N → B-ladder boranes through cobalt-mediated cyclotrimerization of (2-cyanophenyl)-dimesitylborane with different dialkynes. The resulting tetracoordinate boranes show variable electrochemical and optical prope

2,3-Dihalo- and 2,3,6,7-Tetrahaloanthracenes by Vollhardt Trimerization

We efficiently synthesized otherwise difficult to obtain 2,3- and 2,3,6,7-halogenated anthracenes with diverse east/west substituents. Key steps involve the (i) Vollhardt cyclization of bis(propargyl)benzenes with bis(trimethylsilyl)acetylene, (ii) halo-desilylation introducing chlorine, bromine, or iodine substituents, and (iii) dehydrogenation. Pd catalysis allows selective functionalization at the anthracenes' east/west positions. A tetrahydropentacene is synthesized and derivatized via the same strategy, employing tetrapropargylbenzene.

Rhodium dinaphthocyclooctatetraene complexes: Synthesis, characterization and catalytic activity in [5+2] cycloadditions

Rh COT in the act: A Ni0-catalyzed [2+2+2+2] cycloaddition provides a high-yielding, scalable synthesis of the ligand dinaphtho[a,e] cyclooctatetraene (dnCOT). dnCOT complexation with RhI gives [Rh(dnCOT)(MeCN)2]SbF6

Homologation method for preparation of substituted pentacenes and naphthacenes

Multi-substituted pentacenes, such as 1,2,3,4,6,8,9,10,11,13- decasubstituted pentacenes (Type I), 1,2,3,4,6,-13-hexasubstituted pentacenes (Type II), 1,2,3,4-tetrasubstituted pentacenes (Type III), and 2,3-disubstituted pentacenes (Type IV), 1,2,3,4,6,11

254. Synthesis of Cyclopropanthracenes via Trapping of o-Naphthoquinodimethane

Cyclopropanthracenes 1, 1a, 1b are prepared in a 3-step synthesis starting from o-di(iodomethyl)benzene.The key step consists of trapping of o-naphthoquinodimethane (9) with 1,2-di- and tetrahalogenocyclopropenes (3, 3a, 4b).