504398-76-9Relevant academic research and scientific papers
Reaction of a diphosphene complex with dimethylcyanamide
Huy, Ngoc Hoa Tran,Ricard, Louis,Mathey, Francois
, p. 1346 - 1347 (2003)
The reaction of the diphenyldiphosphene[W(CO)5]3 complex 1 with N,N-dimethylcyanamide affords complex 2, resulting from the formal addition of one H and one N=CH-NMe2 unit onto the P=P double bond of 1 as the major product. A bicyclic complex (3) probably resulting from an initial substitution of one cis-CO of each [P-W(CO)5] group by the cyanamide is also formed. Both 2 and 3 have been characterized by X-ray crystal structure analysis.
