504411-52-3Relevant academic research and scientific papers
Synthesis, Structures, and Catalytic Properties of Dinuclear Iridium(I) Complexes with a Hexadentate Macrocyclic Diamine-Tetracarbene Ligand
Fei, Fan,Lu, Taotao,Yang, Chu-Fan,Chen, Xue-Tai,Xue, Zi-Ling
, p. 1595 - 1602 (2018/04/24)
Two dinuclear macrocyclic IrI NHC complexes, [Ir2(L1)(COD)2](PF6)2 (1, COD = 1,5-cyclooctadiene) and [Ir2Cl(L1)(COD)]Cl (2), were prepared by the reaction between [{Ir
Electronic and Steric Tuning of an Atropisomeric Disulfoxide Ligand Motif and Its Use in the Rh(I)-Catalyzed Addition Reactions of Boronic Acids to a Wide Range of Acceptors
Zhao, Guang-Zhen,Foster, Daven,Sipos, Gellért,Gao, Pengchao,Skelton, Brian W.,Sobolev, Alexandre N.,Dorta, Reto
, p. 9741 - 9755 (2018/09/06)
A novel chiral disulfoxide ligand pair bearing fluorine atoms at the 6 and 6′ position of its atropisomeric backbone, (M,S,S)- and (P,S,S)-p-Tol-6F-BIPHESO, was synthesized. Complexation to a rhodium(I) precursor gave rise to μ-Cl- and μ-OH-bridged rhodiu
Rhodium-catalyzed conjugate addition of arylindium reagents to α,β-unsaturated carbonyl compounds
Tato, Rubén,Riveiros, Ricardo,Pérez Sestelo, José,Sarandeses, Luis A.
experimental part, p. 1606 - 1611 (2012/03/11)
A novel rhodium-catalyzed conjugate addition of indium reagents to electron deficient olefins is reported. The reaction takes place in THF/MeOH at 110 °C using arylindium dichlorides, a rhodium(I)-binap complex as catalyst, and α,β-unsaturated ketones and
