504413-97-2Relevant academic research and scientific papers
A Rapid and Efficient Synthesis of a Bifunctional β-Silylketone, Precursor for a Solid Supported β-Silylethanol Anchoring Group
Date, Sonali M.,Iyer, Prema,Ghosh, Sunil K.
, p. 405 - 411 (2007/10/03)
A concise synthesis of 3-dimethyl(phenyl)silyl-5-oxo-hexanoic acid 1, the precursor for a solid supported β-silylethanol anchoring group has been achieved from ethyl 2-ethoxycarbonyl-3-dimethyl(phenyl)silyl-2-propenoate 2 featuring amino acid catalysed Mi
An expeditious synthesis of a β-silylethanol anchoring group by a silicon directed Baeyer-Villiger oxidation on solid-phase
Iyer, Prema,Ghosh, Sunil K.
, p. 9437 - 9440 (2007/10/03)
A concise synthesis of a β-silylethanol anchoring group on an aminomethylated Merrifield resin has been achieved from 3-dimethyl(phenyl)silyl-5-oxohexanoic acid featuring a solid-phase silicon directed Baeyer-Villiger oxidation of a β-silylketone as the key step.
