504414-69-1Relevant academic research and scientific papers
An exceptionally mild catalytic thioester aldol reaction inspired by polyketide biosynthesis
Lalic, Gojko,Aloise, Allen D.,Shair, Matthew D.
, p. 2852 - 2853 (2003)
This report details our discovery of a new catalytic ester aldol reaction using malonic acid half thioesters (MAHTs) that directly affords β-hydroxythioesters. The reaction is catalyzed by combination of a Cu(II) salt and an amine base, and it can be perf
Bioinspired metal-catalysed Doebner-Knoevenagel condensations between malonic acid half thioesters and aldehydes
Berrue, Fabrice,Antoniotti, Sylvain,Thomas, Olivier P.,Amade, Philippe
, p. 1743 - 1748 (2008/02/08)
Inspired by polyketide biosynthesis, unprecedented metal-catalysed Doebner-Knoevenagel condensations between Malonic Acid Half Thioesters (MAHTs) and various aldehydes have been achieved through the use of Yb(OTf)3 as catalyst, mimicking a five
Lanthanoid Complex as a Novel Carbon Dioxide Carrier for the Carboxylation of Active Methylene Compounds under Mild Conditions
Abe, Hiroshi,Inoue, Shohei
, p. 1197 - 1198 (2007/10/02)
A lanthanoid complex, formed by the addition of a lanthanoid alkoxide to an isocyanate, serves as a novel carbon dioxide carrier for the rapid carboxylation of active methylene compounds under mild conditions.
