50460-02-1Relevant academic research and scientific papers
Use of carbon-sulfur cathodes in electro-organic chemistry - Part 2 - Reactions with activated alkenes; evidence for a vicarious substitution specific of this type of electrode.
Guillanton, G. Le,Do, Q. T.,Simonet, J.
, p. 427 - 439 (2007/10/02)
The sulfur-carbon electrode, used as a cathode, appears to be an excellent source of nucleophiles which are good sulfuration reagents towards alkenes not substituted by leaving groups.However, the electrochemical reactions are often complex.It should be w
Variable Reaction Pathways for the Action of Polysulfide on Michael Acceptors
LaLonde, Robert T.,Florence, Robert A.,Horenstein, Benjamin A.,Fritz, Richard C.,Silveira, Linda,et al.
, p. 85 - 91 (2007/10/02)
α,β-Unsaturated enones and cinnamaldehyde are treated with ethanolic sodium polysulfide and the product mixtures are analyzed to ascertain the types of products. 2'-Methoxychalcone reacts to give a thiolane wherein C-2 of one chalcone unit forms a carbon-
