50482-95-6

Upstream product

• 23695-65-0 adamantane-2-thione 
• 300539-07-5 cis-3,5-di-tert-Butyl-3,5-di-p-tolyl-1,2,4-trithiolane 
• 30314-44-4 2,2-dimethyl-1-(4-methylphenyl)-1-propanone 
• 50482-96-7 p-methylthiopivalophenone S-oxide 
• 261736-83-8 p-phenoxythiopivalophenone 

Downstream Products

• 30314-44-4 2,2-dimethyl-1-(4-methylphenyl)-1-propanone 
• 50482-96-7 p-methylthiopivalophenone S-oxide 

Relevant academic research and scientific papers

Synthesis of 1,2,4-Trithiolanes from Thione S-Oxides and Lawesson Reagent at Room Temperature

The reaction of 2,2,4,4-tetramethyl-3-thioxocyclobutanone S-oxide with Lawesson reagent (L. R.) afforded the corresponding 1,2,4-trithiolane. Thiopivalophenone and thiopivalophenone S-oxides reacted with L. R. at rt to give the corresponding S-sulfide, which further reacted with thiones to afford the corresponding cis-1,2,4-trithiolanes.

A new simple synthesis of cis- and trans-3,5-di-tert-butyl-3,5-diaryl-1,2,4-trithiolanes from ketones and tetraphosphorus decasulfide

The reaction of pivalophenones with tetraphosphorus decasulfide afforded cis- and trans-3,5-di-tert-butyl-3,5-diaryl-1,2,4-trithiolanes, which equilibrated to give other isomers in refluxing toluene via thiopivalophenones and thiopivalophe-none S-sulfides.