50517-71-0Relevant articles and documents
Catalytic Dehydrogenation of Amine-Boranes using Geminal Phosphino-Boranes
Boom, Devin H. A.,de Boed, Ewoud J. J.,Nicolas, Emmanuel,Nieger, Martin,Ehlers, Andreas W.,Jupp, Andrew R.,Slootweg, J. Chris
, p. 586 - 592 (2020/02/11)
The reaction of the intramolecular frustrated Lewis pair (FLP) tBu2PCH2BPh2 with the amine-boranes NH3·BH3 and Me2NH·BH3 leads to the formation of the corresponding FLP-H2/
Three aryl boron fluorescent compound and its preparation and use
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Paragraph 0054; 0055; 0056; 0057, (2017/04/12)
The invention discloses a series of triaryl boron fluorescent compounds and a nanometer aquagel fluorescent sulfydryl probe based on the triaryl boron fluorescent compounds. The triaryl boron fluorescent compounds are characterized by excellent selectivity to sulfydryl compounds, so that the triaryl boron fluorescent compounds can be used as fluorescent probes for detecting sulfydryl compounds in an organic solution or an organic-water mixed solution. The nanometer aquagel fluorescent sulfydryl probes based on the triaryl boron fluorescent compound can not only be used for detecting the sulfydryl compounds in an aqueous solution or a buffer solution, but also be used in sulfydryl compound single-photon or dual-photon fluorescent imaging in cells because of the availability of self-entering into the cells. The fluorescent probe has the advantages of high sensibility, fast response speed, good specificity, low biotoxicity, wide response range and the like.
DIMESITYLBORYL COMPOUNDS. PART III. OXYGEN DERIVATIVES
Brown, N.M.D.,Davidson, F.,McMullan, R.,Wilson, J.W.
, p. 271 - 282 (2007/10/02)
A series of alkoxy and aryloxydimesitylboranes (Mes2BOR) has been synthesised, characterised and their 1H, 11B and 13C NMR data recorded.The corresponding data for fluorodimesitylborane is reported.As has been found for other dimesitylboryl systems, the mesityl 13C chemical shifts remain virtually unchanged with change in R.It is concluded that there is no B-aryl ? backbonding in Mes2BX systems and that B-X ? bonding increases in the order N>O>F>>C.