50598-99-7Relevant academic research and scientific papers
Regioselectivity in the rhodium catalysed 1,4-hydrosilylation of isoprene. Aspects on reaction conditions and ligands
Gustafsson, Magnus,Frejd, Torbj?rn
, p. 438 - 443 (2004)
The regioselectivity in the Rh catalysed 1,4-hydrosilylation of isoprene was investigated. Variation of solvents and temperature did not significantly affect the isomer distribution between tail-product (I) and head-product (II). The choice of ligands had
Selective addition of hydrosilanes to 1,3-dienes catalyzed by polyamine-supported metal complex catalysts
Michalska, Zofia M.,Ostaszewski, Bogdan,Strzelec, Krzysztof
, p. 19 - 26 (1995)
Four transition metal complexes 2, PdCl2(PhCN)2, PtCl2(PhCN)2 and RuCl2(bipy)2 were immobilized on polyamides bearing a pyridine moiety in their repeat units and displaying a relatively uniform distribution of micropores with voids from 1.0 to 3.0 nm.The polymer-supported catalysts were used in the hydrosilylation of isoprene and 2-methyl-1,3-pentadiene with the purpose of investigating the effect of polymer morphology on the catalyst selectivity.The addition of HSiMe2Ph and HSi(EtO)3 to both 1,3-dienes catalyzed by the polymer-supported Rh(I) catalysts wasfound to proceed highly regioselectively and stereoselectively to give (Z)-(2-methyl-but-en-2-en-1-yl)silanes and (Z)-(2-methyl-pent-2-en-1-yl)silanes as the predominant products (85-95percent).The stereochemical assignment of the products was carried out by 1H NMR spectroscopy employing the nuclear Overhauser effect.A similar 1,4-addition of Me2PhSiH to isoprene and 2-methyl-1,3-pentadiene was found to produce Z isomers as the main products for the polymer-supported Pd(II) catalysts.In contrast the same reaction with HSi(EtO)3 proceeded via a 1,2 route with 79-85percent selectivity.As a general feature, in all the reactions studied, exception for the hydrosilylations catalyzed by polymer-supported rhodium catalysts, the 1,4 mode of addition prevailed with HSiMe2Ph, but 1,2 addition with HSi(EtO)3.Essentially the same regioselectivity was found for reactions under the homogeneous conditions.These results demonstrated that the microporous structure of the polyamide supports did not exert any particular effect on the regioselective and stereoselective course of the reaction.The explanation was based on a good match of the dimensions of thereaction intermediate to those of the polymer micropores.The constant selectivity of the supported catalysts demonstrated during recycling tests showed that they could be useful for practical application. Keywords: Rhodium; Platinum; Palladium; Catalysis; Hydrosilylation, Polymer-supported catalysis
The effect of oxygen on the regioselectivity in the rhodium catalysed hydrosilylation of 1,3-dienes
Gustafsson, Magnus,Frejd, Torbjoern
, p. 102 - 107 (2007/10/03)
The regioselectivity of the hydrosilylation of substituted 1,3-dienes catalysed by several rhodium complexes in the presence and absence of oxygen was studied. In addition to the already known accelerating effect, the presence of oxygen strongly affected
