506441-57-2

Basic information

• Product Name: 2,5,7-Metheno-1H-cyclopenta[a]pentalen-3-ol,decahydro-,(2S,3R,3aS,3bS,5S,6aR,7R,7aR,8R)-(9CI)
• Synonyms: 2,5,7-Metheno-1H-cyclopenta[a]pentalen-3-ol,decahydro-,(2S,3R,3aS,3bS,5S,6aR,7R,7aR,8R)-(9CI)
• CAS NO: 506441-57-2
• Molecular Formula: C12H16O
• Molecular Weight: 176.25
• Product Categories: CYCLOHEXANE
• Mol File: 506441-57-2.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,5,7-Metheno-1H-cyclopenta[a]pentalen-3-ol,decahydro-,(2S,3R,3aS,3bS,5S,6aR,7R,7aR,8R)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5,7-Metheno-1H-cyclopenta[a]pentalen-3-ol,decahydro-,(2S,3R,3aS,3bS,5S,6aR,7R,7aR,8R)-(9CI)(506441-57-2)
• EPA Substance Registry System: 2,5,7-Metheno-1H-cyclopenta[a]pentalen-3-ol,decahydro-,(2S,3R,3aS,3bS,5S,6aR,7R,7aR,8R)-(9CI)(506441-57-2)

Safety Data

• Hazardous Substances Data: 506441-57-2(Hazardous Substances Data)

Usage

Structure

cyclopentane ring structure with a hydroxyl group

Potential Applications

pharmaceuticals, perfumes, industrial processes

Stereochemistry

(2S,3R,3aS,3bS,5S,6aR,7R,7aR,8R) indicating spatial arrangement of atoms

Complexity

complex chemical compound with intriguing potential for study and applications in various industries.

Upstream product

• 7509-41-3 C₁₂H₁₄O 
• 506441-55-0 (+/-)-exo-pentacyclo[6.2.1.1^3,6.0^2,7.0^5,9]dodecan-4-ol 
• 506441-55-0 (+)-exo-pentacyclo[6.2.1.1^3,6.0^2,7.0^5,9]dodecan-4-ol 
• 108-05-4 vinyl acetate 
• 15914-94-0 exo-endo-tetracyclo[4.4.1^2,5.1^7,10.0^1,6]dodeca-3,8-diene 

Relevant articles and documents

Asymmetric synthesis of half-cage alcohol compounds

To obtain enantiopure pentacyclic chlorinated and dechlorinated alcohols, we evaluated various synthetic routes. Enantiopure acetate (-)-5 (ee >95%) was obtained from an enantioselective inversion of a stereogenic center of the pentacyclic acetate (+)-4 in an acidic medium. Conversely, enantiopure alcohols (+)-11 and (+)-15 were obtained by the kinetic resolution of alcohol (±)-11 by transesterification using lipase from Candida rugosa. It was verified that the lipase recognized alcohol (±)-11, producing the alcohol (+)-11 (ee >98%) and acetate (-)-13 (ee >99%) with a high degree of enantioselectivity (E >100) and a conversion of 50% after only 1 h.