50652-79-4Relevant academic research and scientific papers
Tertiary mercaptoketone, and fragrance and flavor composition containing the same
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Page/Page column 13, (2010/02/12)
[PROBLEM TO BE SOLVED]: To provide a new fragrance and flavor element which have high acceptability, excel in odorant, flavor, depth, etc., and can be useful as a flavor seasoning substance for various products effectively, and to provide a fragrance and a flavor composition containing the same. [SOLUTION]: The tertiary mercaptoketone shown by following formula(I): [Wherein, R and R' are the same or different C1-C3 alkyl group; and the total carbon number of R and R' is 3 or 4], the method for producing the compound, and the fragrance and flavor composition containing the compound.
Reaction of Diketene with Grignard Reagents in the Presence of Cobalt Catalyst. A Convenient Method for the Synthesis of 3-Methylenealkanoic Acids Leading to Terpenoids
Fujisawa, Tamotsu,Sato, Toshio,Gotoh, Yoshihiko,Kawashima, Masatoshi,Kawara, Tatsuo
, p. 3555 - 3559 (2007/10/02)
Primary alkyl Grignard reagents react regioselectively with diketene in the presence of cobalt(II) iodide to afford 3-methylenealkanoic acids in good yields.The synthetic utility of this reaction is demonstrated in the syntheses of terpenoids by two methods.Utilizing the isomerization of double bond of 3-methylenealkanoic acids, geranic acid and farnesic acid were obtained in two steps.Another method, the tandem sigmatropic rearrangement of the corresponding allylic esters was used for the synthesis of C18-Cecropia juvenile hormone.
