50663-45-1Relevant academic research and scientific papers
Kinetics of reactions of chlorinated vinyl radicals CH2CCl and C2Cl3 with molecular oxygen
Russell,Seetula,Gutman,Senkan
, p. 1934 - 1938 (1989)
The kinetics of the reactions of CH2CCl and C2Cl3 radicals with O2 have been studied in a tubular flow reactor coupled to a photoionization mass spectrometer in the temperature range 298-648 K. Radicals were produced by the homogeneous photolysis of a suitable precursor using an excimer laser. The observed or indicated reaction mechanisms as well as the rate constants, which were measured as a function of density and temperature, suggest that both of these reactions proceed via the formation of a short-lived bound RO2 intermediate that can either decompose back to the original reactants or form new oxygen-containing products following internal rearrangement of the adduct.
