50708-37-7

Usage

InChI:InChI=1/C10H12S4/c1-5-6(2)12-9(11-5)10-13-7(3)8(4)14-10/h1-4H3

Upstream product

• 88070-48-8 N-methylbenzamide 
• 74731-83-2 2-methoxy-4,5-dimethyl-1,3-dithiole 
• 117156-72-6 (4,5-Dimethyl-[1,3]dithiol-2-ylidene)-triphenyl-λ⁵-phosphane 
• 65220-65-7 Triphenyl-(4,5,6,7-tetrahydro-benzo[1,3]dithiol-2-ylidene)-λ⁵-phosphane 
• 141192-76-9 hexafluorophosphate de 4-methyl-1,3-dithiolium-2-triphenylphosphonium 
• 107907-69-7 hexafluorophosphate de 4,5-dimethyl-1,3-dithiolium-2-triphenylphosphonium 
• 103-84-4 Acetanilid 
• 1518-16-7 7,7',8,8'-tetracyanoquinodimethane 
• 118-75-2 chloranil 
• 4587-25-1 2,3-dibromo-5,6-dicyano-1,4-benzoquinone 
• 17534-27-9 4,5-dimethyl-[1,3]dithiole-2-thione 
• 158871-28-4 4,5-bis(2-cyanoethylthio)-1,3-dithiol-2-one 
• 118-75-2 chloranil anion radical 
• 1518-16-7 7,7,8,8-tetracyanoquinodimethane radical anion 

Downstream Products

• 1518-16-7 7,7,8,8-tetracyanoquinodimethane radical anion 
• 118-75-2 chloranil anion radical 
• 1518-16-7 7,7',8,8'-tetracyanoquinodimethane 
• 118-75-2 chloranil 
• 4587-25-1 2,3-dibromo-5,6-dicyano-1,4-benzoquinone 
• 1330094-66-0 C₁₀H₂N₄*C₁₀H₁₂S₄ 
• 50708-38-8 4,4',5,5'-Tetramethyl-Δ^2,2'-bis-1,3-dithiol 7,7,8,8-Tetracyano-p-chinodimethan 
• 73075-23-7 2-(4-Dicyanomethylene-2,5-diethyl-cyclohexa-2,5-dienylidene)-malononitrile; compound with 4,5,4',5'-tetramethyl-[2,2']bi[[1,3]dithiolylidene] 

Relevant academic research and scientific papers

Preparation and chemistry of new unsymmetrically substituted tetrachalcogenofulvalenes bearing CN(CH2)2X and HO(CH2)2X groups (X = S or Se)

Several unsymmetrically substituted TTFs bearing the S(CH2)2CN protecting group have been prepared by standard cross coupling in triethyl phosphite from the key intermediate 4,5-bis(2′-cyanqethylsulfanyl)-1,3-dithiol-2-one 1 and an a

SYNTHESES ET CARACTERISATION DES DERIVES METHYLES DU TETRATHIAFULVALENE; NOUVELLE VOIE D'ACCES AU TETRATHIAFULVALENE

We propose an improved general method for the synthesis of tetrathiafulvalene and its methylated derivatives.TTF is obtained in a five steps preparation offering a high Overall yield. Concerning the unsymmetrically methylated tetrathiafulvalenes, four different procedures are analysed.It is shown the best routes to prepare trimethyltetrathiafulvalene are a WITTIG type reaction, and a selective synthesis based on a WITTIG-HORNER reaction.The monomethyltetrathiafulvalene has been isolated in a 96percent state of purity.

Synthesis of unsimmetrically substituted tetrathiafulvalenes by the "ylid route". Investigations of selectivity.

The selective synthesis of unsimmetrically substituted tetrathiafulvalenes 1 (R R') using phosphonium ylids 2 and dithiolium salts 3 in THF at -80 deg C has been investigated.Several unsymmetrical tetrathiafulvalenes were obtained in good yield. R,R'=CH3; (CH2)4; o-C6H4.It was also shown that the instability of the phosphonium ylid 2 and dithiolylium 3 under the rreaction conditions leads to the formation of variable amounts of symmetrical terathiafulvalenes 1 (R = R').Therefore, purification of the mixture by column chromatography with CS2 as eluent was necessary.

NEW CONDUCTING SALTS CONTAINING UNSYMMETRICAL ?-DONORS

This communication describes the synthesis and the electrochemical properties of a new type of donor containing sulfur or selenium atoms: the dimethyltetramethylenetetraselenafulvalene 1 and the dimethyltetramethylenetetrathiafulvalene 2.The electrical conductivity of their charge transfer complexes and of some of their radical cation salts are reported.

INSERTION OF 1,3-DITHIOLIUM CARBENES INTO N-H BOND OF AMIDES AND IMIDES

It was found that 1,3-dithiolium carbenes (4a-d) generated from 2-methoxy-1,3-dithioles (1a-d) were inserted into N-H bond of N-methylbenzamide, acetanilide and succinimide to form N-(1,3-dithiol-2-yl)amides (imides) 8-10, respectively.It was shown that N

REACTIONS OF 1,3-DITHIOLIUM CARBENES IN SITU WITH AROMATIC ALDEHYDES

It was found that 1,3-dithiolium carbenes (3) generated from various 1,3-dithiole derivatives reacted with aromatic aldehydes to form 2-benzoyl-2,2'-(1',3'-dithiolyl)-1,3-dithioles (6).The proposed mechanism of reaction has been discussed.