50708-37-7Relevant articles and documents
Preparation and chemistry of new unsymmetrically substituted tetrachalcogenofulvalenes bearing CN(CH2)2X and HO(CH2)2X groups (X = S or Se)
Binet, Laurent,Fahre, Jean Marc,Montginoul, Claude,Simonsen, Klaus Baek,Becher, Jan
, p. 783 - 788 (2007/10/03)
Several unsymmetrically substituted TTFs bearing the S(CH2)2CN protecting group have been prepared by standard cross coupling in triethyl phosphite from the key intermediate 4,5-bis(2′-cyanqethylsulfanyl)-1,3-dithiol-2-one 1 and an a
Synthesis of unsimmetrically substituted tetrathiafulvalenes by the "ylid route". Investigations of selectivity.
Fabre, J. M.,Giral, L.,Gouasmia, A.,Cristau, H. J.,Ribeill, Y.
, p. 823 - 826 (2007/10/02)
The selective synthesis of unsimmetrically substituted tetrathiafulvalenes 1 (R R') using phosphonium ylids 2 and dithiolium salts 3 in THF at -80 deg C has been investigated.Several unsymmetrical tetrathiafulvalenes were obtained in good yield. R,R'=CH3; (CH2)4; o-C6H4.It was also shown that the instability of the phosphonium ylid 2 and dithiolylium 3 under the rreaction conditions leads to the formation of variable amounts of symmetrical terathiafulvalenes 1 (R = R').Therefore, purification of the mixture by column chromatography with CS2 as eluent was necessary.
INSERTION OF 1,3-DITHIOLIUM CARBENES INTO N-H BOND OF AMIDES AND IMIDES
Buza, Daniela,Gradowska, Wanda
, p. 1059 - 1069 (2007/10/02)
It was found that 1,3-dithiolium carbenes (4a-d) generated from 2-methoxy-1,3-dithioles (1a-d) were inserted into N-H bond of N-methylbenzamide, acetanilide and succinimide to form N-(1,3-dithiol-2-yl)amides (imides) 8-10, respectively.It was shown that N