50717-35-6Relevant academic research and scientific papers
Diarylamine Synthesis via Desulfinylative Smiles Rearrangement
Butterworth, Sam,Greaney, Michael F.,Large, Jonathan M.,Sephton, Thomas
supporting information, (2022/02/09)
Diarylamines are obtained directly from sulfinamides through a novel rearrangement sequence. The transformation is transition metal-free and proceeds under mild conditions, providing facile access to highly sterically hindered diarylamines that are otherw
Copper-catalyzed intermolecular amination of acidic aryl C-H bonds with primary aromatic amines
Zhao, Huaiqing,Wang, Min,Su, Weiping,Hong, Maochun
supporting information; experimental part, p. 1301 - 1306 (2010/07/03)
A copper-catalyzed intermolecular aerobic oxidative C-H bond amination of various polyfluorobenzenes with an array of primary aromatic amines was achieved for the first time. The reactivity of the polyfluorobenzenes was observed to depend on the acidity of C-H bonds. Under similar reaction conditions, the C-H bond amination of azoles also occurred.
KINETICS OF THE REACTION OF THE N-ANIONS OF ARYL- AND DIARYLAMINES WITH p-NITROFLUOROBENZENE IN DIMETHYL SULFOXIDE
Vlasov, V. M.,Os'kina, I. A.
, p. 1587 - 1592 (2007/10/03)
The rate constants for the reactions of the sodium salts of the N-anions of aryl- and diarylamines of identical basicity with p-nitrofluorobenzene in DMSO at 25 deg C have similar values.The Broensted coefficient βNu for the investigated series
