507480-05-9

Upstream product

• 507480-04-8 (2R,4R)-2-(4-methoxyphenyl)-4-((S)-1-methyl-prop-2-enyl)-[1,3]dioxane 
• 128461-65-4 3-(p-methoxybenzyloxy)propanal 

Downstream Products

• 652986-40-8 (R)-3-[(2R,4R)-2-(4-Methoxy-phenyl)-[1,3]dioxan-4-yl]-butan-2-one 
• 507480-04-8 (2R,4R)-2-(4-methoxyphenyl)-4-((S)-1-methyl-prop-2-enyl)-[1,3]dioxane 
• 259656-95-6 (3R,4S)-3-(4-methoxybenzyloxy)-4-methyl-5-hexen-1-ol 
• 412909-38-7 (3R,4S)-3-(4-methoxybenzyloxy)-4-methylhex-5-enoic acid 
• 507480-28-6 4-Nitro-benzoic acid (1S,3R,4S)-1-allyl-3-(4-methoxy-benzyloxy)-4-methyl-hept-6-ynyl ester 
• 507480-26-4 (4R,6R)-4-allyl-2-(4-methoxyphenyl)-6-[(1S)-1-methylbut-3-ynyl]-1,3-dioxane 
• 507480-08-2 (4R,6R,7S)-6-(4-Methoxy-benzyloxy)-7-methyl-dec-1-en-9-yn-4-ol 
• 507480-07-1 (3R,4S)-3-(4-Methoxy-benzyloxy)-4-methyl-hept-6-yn-1-ol 
• 507480-06-0 (2R,4R)-2-(4-Methoxy-phenyl)-4-((S)-1-methyl-but-3-ynyl)-[1,3]dioxane 
• 507480-25-3 (3R,4S)-3-(4-Methoxy-benzyloxy)-4-methyl-hept-6-ynal 
• 507480-23-1 Toluene-4-sulfonic acid (S)-2-[(2R,4R)-2-(4-methoxy-phenyl)-[1,3]dioxan-4-yl]-propyl ester 

Relevant academic research and scientific papers

A Non-Aldol Preparation of Enantiopure Propionate-Derived Motifs with the Assistance of Chiral Sulfoxides: Application to a Convergent Synthesis of the Lactone Core of Octalactins

Propionate-derived fragments were prepared by a non-aldol method using chiral sulfoxide chemistry. A methacrylate ester, assisted by a chiral sulfoxide as an auxiliary agent, was easily transformed into an optically pure allylic alcohol, which was then su

Stereoselective Aldol-Type Cyclization Reaction Mediated by Dibutylboron Triflate/Diisopropylethylamine

(Equation presented) Dibutylboron triflate/diisopropylethylamine mediated aldol-type cyclization provides an expedient route for the stereoselective synthesis of cyclic ethers in a single step. The method is highly efficient for the stereoselective synthe

Formal total synthesis of salicylihalamides A and B

An efficient synthesis of the macrolactone 3 of the salicylihalamides in 10 linear steps from alkene 6 is described. The key steps involved a Stille coupling between the chiral stannane 5 and benzyl bromide 4, which produced alkene 15 in good yield, and subsequent base-induced macrolactonization then gave compound 3. Macrolactone 3 was then converted into the known salicylihalamide A intermediate 18 in a three-step sequence. Compound 3 was also converted into another known salicylihalamide A and B intermediate 23 in a five-step sequence.