412909-38-7

Upstream product

• 412909-37-6 C₃₅H₃₈O₄ 
• 412908-67-9 (3R,4S)-5-(tert-butyldiphenylsilyloxy)-4-methylpent-1-en-3-ol 
• 158497-90-6 tert-Butyl-[(2S,3R)-3-(4-methoxy-benzyloxy)-2-methyl-pent-4-enyloxy]-diphenyl-silane 
• 259656-95-6 (3R,4S)-3-(4-methoxybenzyloxy)-4-methyl-5-hexen-1-ol 
• 158497-91-7 (2S,3R)-3-(4-Methoxy-benzyloxy)-5-[(4-methoxy-phenyl)-diphenyl-methoxy]-2-methyl-pentan-1-ol 
• 412908-78-2 (3R,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-3-(4-methoxy-benzyloxy)-4-methyl-pentan-1-ol 
• 507480-04-8 (2R,4R)-2-(4-methoxyphenyl)-4-((S)-1-methyl-prop-2-enyl)-[1,3]dioxane 
• 507480-05-9 (2S)-2-[(4R)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]propan-1-ol 

Downstream Products

• 412908-65-7 (3R,4S)-3-(4-Methoxy-benzyloxy)-4-methyl-hex-5-enoic acid (S)-1-[(R)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-allyl ester 

Relevant academic research and scientific papers

A Non-Aldol Preparation of Enantiopure Propionate-Derived Motifs with the Assistance of Chiral Sulfoxides: Application to a Convergent Synthesis of the Lactone Core of Octalactins

Propionate-derived fragments were prepared by a non-aldol method using chiral sulfoxide chemistry. A methacrylate ester, assisted by a chiral sulfoxide as an auxiliary agent, was easily transformed into an optically pure allylic alcohol, which was then su

Total synthesis of octalactin A via ring-closing metathesis reaction

A new total synthesis of the novel lactone natural product octalactin A is described. The key step involves the facile construction of the eight-membered lactone core via ring-closing metathesis (RCM). This oxocene was elaborated to give the powerful anti