5076-50-6

Usage

Uses

Used in Organic Synthesis:
(1E)-1,3-bis(3-nitrophenyl)triaz-1-ene is used as a reactant in organic synthesis for its ability to participate in a wide range of chemical reactions. Its versatility in forming different types of chemical bonds and its compatibility with various reaction conditions make it a popular choice among chemists.
Used in Materials Chemistry:
In materials chemistry, (1E)-1,3-bis(3-nitrophenyl)triaz-1-ene is used as a building block for the synthesis of new functional materials. Its structural features allow it to be incorporated into the design and fabrication of advanced materials with specific properties for various applications.
Used in Pharmaceutical Industry:
(1E)-1,3-bis(3-nitrophenyl)triaz-1-ene has potential applications in the pharmaceutical industry. Its unique chemical properties and reactivity make it a promising candidate for the development of new drugs and therapeutic agents. Researchers are exploring its potential in creating novel pharmaceutical compounds with improved efficacy and selectivity.
Overall, (1E)-1,3-bis(3-nitrophenyl)triaz-1-ene is a versatile chemical compound with a broad range of applications in organic synthesis, materials chemistry, and the pharmaceutical industry. Its unique properties and reactivity make it an important tool for chemists and researchers in these fields.

Upstream product

• 99-09-2 3-nitro-aniline 
• 10544-72-6 dinitrogen tetraoxide 
• 71-43-2 benzene 
• 100-05-0 4-nitrobenzenediazonium chloride 

Downstream Products

• 62406-72-8 2,4,6-tribromo-3-nitro-aniline 
• 36647-25-3 N-(3-nitrophenyl)phthalimide 
• 91731-83-8 C₁₄H₁₁N₅O₅ 
• 121-73-3 3-Nitrochlorobenzene 
• 99-09-2 3-nitro-aniline 
• 100-05-0 4-nitrobenzenediazonium chloride 
• 861532-43-6 5-nitro-1-(3-nitrophenyl)-1H-benzo[d][1,2,3]triazole 
• 326017-46-3 3-methyl-1,3-bis-(3-nitro-phenyl)-triazene 
• 321531-25-3 3-ethyl-1,3-bis-(3-nitro-phenyl)-triazene 

Relevant academic research and scientific papers

Pd-catalyzed C-H activation/C-N bond formation: A new route to 1-aryl-1H-benzotriazoles

A method for the C-H activation of aryl triazene compounds followed by intramolecular amination is described. It involves the use of a catalytic amount of Pd(OAc)2 that efficiently effects the cyclization to provide 1-aryl-1H-benzotriazoles at moderate temperature.

1,3-Bis(3-nitrophenyl)triazene

The title molecule, C12H9N5O4, has trans geometry about the azo linkage. The dihedral angle between the two phenyl rings is 6.2(2)°. The whole molecule is almost planar and the maximum deviation from the mean plane is 0.166 (3) A. The resonance effect in the triazene group which might explain the antitumour activity of some triazene derivatives is discussed. In the crystal structure, while the twofold screw-related molecules are packed in a simple herringbone pattern, the inversion-centre-related molecules form hydrogen-bonded dimers which are held together through π...π interactions along the [010] direction.

Nitrosation with Sodium Hexanitrocobaltate(III)

Na3Co(NO2)6 has been investigated as a new reagent for the nitrosation of various substrates containing an amino functionality. Reactions took place in an aqueous solution of the reagent. The pH of the reaction mixture remained in the range 4.3-5. Thus, hydrazides were transformed to the corresponding acyl azides, and the reactions with arenesulfonyl hydrazines afforded arenesulfonyl azides. Treatment of aromatic amines with Na3Co(NO2)6 gave 1,3-diaryltriazenes in excellent yields; coupling of the initially formed diazo compound to the electron rich aromatic ring was also observed. Nitrosation of aliphatic amines was not possible due to complex formation with the reagent.

SUBSTITUENT EFFECT ON SOLVOLYSIS OF 3-ACETYL-1,3-DIPHENYLTRIAZENES

Eleven symmetrically disubstituted 3-acetyl-1,3-diphenyltriazenes have been synthetized by a new method.The solvolysis kinetics of title compounds has been measured in 20percent aqueous ethanol at several temperatures.The results are discussed from the point of view of temperature and substituent effects on the solvolysis rate constant of the 3-acetyl-1,3-diphenyltriazenes and conclusions are drawn about the reaction mechanism.