50777-80-5Relevant academic research and scientific papers
H2O as a chemical link for ferromagnetic interactions between aminoxyl units
Rancurel, Corinne,Daro, Nathalie,Borobia, Oscar Benedi,Herdtweck, Eberhardt,Sutter, Jean-Pascal
, p. 167 - 171 (2003)
A bis(radical) derivative based on a triphenylphosphane core substituted by two nitronyl nitroxide units is reported. This compound was isolated in two forms. One consists of an H2O adduct where H2O is hydrogen-bonded to the radical units, whereas the second lacks this bridging unit. Magnetic studies revealed that the presence of the H2O bridge induces ferromagnetic exchange interaction between the spin carriers. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.
