50878-39-2Relevant academic research and scientific papers
Mild and efficient synthesis of carbazates and dithiocarbazates via a three-component coupling using Cs2CO3 and TBAI
Fox, Daniel L.,Ruxer, John T.,Oliver, John M.,Alford, Kasey L.,Salvatore, Ralph Nicholas
, p. 401 - 405 (2007/10/03)
Efficient methods for the synthesis of carbazates and dithiocarbazates have been developed. In the presence of cesium carbonate (Cs2CO 3) and tetrabutylammonium iodide (TBAI) a hydrazine, CO2 or CS2, and an alkyl halide underwent a three-component coupling at room temperature. Various unprotected hydrazines and alkyl halides were examined and the results demonstrated this methodology was highly chemoselective. Applications toward the synthesis of azadepsipeptides and other pseudopeptides are described.
Nickel Complexes of the Methyl Esters of Dithiocarbazic and N-Substituted Dithiocarbazic Acids
Monaci, Anna,Tarli, Franco
, p. 499 - 502 (2007/10/02)
The nickel complexes of the methyl esters of dithiocarbazic acid NH2NHC(=S)SMe (L), 2-methyldithiocarbazic acid NH2NMeC(=S)SMe (MeL), 2-n-butyldithiocarbazic acid, NH2NBuC(=S)SMe (BuL), 3,3-dimethyldithiocarbazic acid NMe2NHC(=S)SMe (Me2L), 3-phenyldithio
