5088-11-9Relevant academic research and scientific papers
A visible-light-induced chemoselective radical/oxidative addition domino process to access α-chloro and α-alkoxy aryl ketones
Niu, Teng-Fei,Jiang, Ding-Yun,Li, Si-Yuan,Ni, Bang-Qing,Wang, Liang
supporting information, p. 13105 - 13108 (2016/11/09)
A visible-light-induced radical-triggered chemoselective domino process to access α,α-di-functionalized ketones under mild conditions has been developed. This protocol provides a direct approach to synthesize α-chloro or α-alkoxy aryl ketones based on the electronic properties of the substrates. The reaction can tolerate a variety of functional groups to afford the corresponding products in moderate to good yields.
"STRUCTURE-REACTIVITY-SELECTIVITY" RELATIONSHIP IN SN2 PROCESSES. REACTION OF 4,4'-SUBSTITUTED α-CHLORODEOXYBENZOINS WITH SODIUM THIOPHENOLATES
Karavan, V. S.,Simonov, D. A.
, p. 145 - 148 (2007/10/02)
In the SN2 reactions of α-chlorodeoxybenzoins X'C6H4CHClCOC6H4X with YC6H4SNa in methanol there is no unambiguous relationship at all between the reactivity of the substrate and its selectivity toward the nucleophile (ρY).At the same
Azole derivatives
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, (2008/06/13)
Azole derivatives of the formula SPC1 Wherein R1 is free or esterified carboxyl or other functionally modified carboxyl group, R2 and R3 each are aryl; A is Cn H2n in which n is an integer from 1 to 10, inclusive; and Z is O or S; and the physiologically acceptable salts thereof, possess, with good compatibility, excellent antiphlogistic activity and, in particular, influence favorably the chronic progressive diseases of the joints, e.g., arthritis. They can be prepared from compounds of the formula SPC2 Wherein X1 is a group convertible into the group --S--A--R1, and R2 and R3 have the values given above.
