50886-35-6Relevant articles and documents
Bis(NHC)-palladium(II) complex-catalyzed dioxygenation of alkenes
Wang, Wenfeng,Wang, Feijun,Shi, Min
experimental part, p. 928 - 933 (2010/05/01)
Bis(NHC)-Pd(II) complexes derived from l,l'-binaphthyl-2,2'-diamine (BINAM) were successfully first used to catalyze the dioxygenation of alkenes under mild conditions tolerant of air and moisture. Cationic NHC-Pd2+ diaquo complex 1e showed the highest catalytic activity to give 1,2dioxygenation products with good syn-diastereoselectivity for 1,2-disubstituted alkenes.
ADDITION OF PHTHALIMIDONITRENE TO RING-SUBSTITUTED STYRENES
Kuznetsov, M. A.,Belov, V. N.
, p. 1611 - 1616 (2007/10/02)
The addition of phthalimidonitrene to 9-ring-substituted styrenes gives 30-70percent yields of the corresponding previously undescribed 2-aryl-1-phthalimidoaziridines.By the method of competing reactions it was shown that phthalimidonitrene exhibits elect