50931-32-3

Upstream product

• 41595-29-3 N,N'-ditosyl-p-phenylenediamine 
• 98-59-9 p-toluenesulfonyl chloride 
• 106-50-3 1,4-phenylenediamine 
• 50931-32-3 (E)-N,N′-(cyclohexa-2,5-diene-1,4-diylidene)bis-(4-methylbenzenesulfonamide) 
• 50931-32-3 (Z)-N,N′-(cyclohexa-2,5-diene-1,4-diylidene)bis-(4-methylbenzenesulfonamide) 

Downstream Products

• 41595-29-3 N,N'-ditosyl-p-phenylenediamine 
• 134645-54-8 [2,5-Bis-(toluene-4-sulfonylamino)-phenyl]-phosphonic acid dimethyl ester 
• 134645-46-8 C₂₂H₂₅N₂O₇PS₂ 
• 93343-25-0 2,5-bis(4-tolylsulfonylamino)-1,4-benzoquinone 
• 332015-33-5 C₂₀H₁₉N₅O₄S₂ 
• 25445-14-1 N,N'-Ditosyl-1,4-diamino-2,5-dibrombenzol 
• 50931-32-3 (E)-N,N′-(cyclohexa-2,5-diene-1,4-diylidene)bis-(4-methylbenzenesulfonamide) 

Relevant academic research and scientific papers

Chiral Phosphoric Acid-Catalyzed Enantioselective Construction of 2,3-Disubstituted Indolines

Highly enantio- and regioselective (3 + 2) formal cycloaddition of β-substituted ene- and thioenecarbamates as well as cyclic enamides with quinone diimides catalyzed by a BINOL- and SPINOL-derived phosphoric acid is reported. A wide variety of 2,3-disubstituted 2-aminoindolines, including polycyclic ones, were prepared in generally high yields (up to 98%) with moderate to complete diastereoselectivities and in most cases excellent enantioselectivities (up to 99% ee).

Synthesis of N,N′-Bis(arylsulfanyl)cyclohexa-2,5-diene-1,4-diimines and N,N′-(Cyclohexa-2,5-diene-1,4-diylidene)bis(arenesulfinamides)

Abstract: Reactions of (chlorosulfanyl)benzenes with benzene-1,4-diamines afforded new N,N′-bis(arylsul-fanyl)cyclohexa-2,5-diene-1,4-diimines which were oxidized to N,N′-(cyclohexa-2,5-diene-1,4-diylidene)-bis(arenesulfinamides) with 2 equiv of m-chloroperoxybenzoic acid. When the oxidation was carried out using 4 equiv of m-chloroperoxybenzoic acid, the corresponding bis-sulfonamides were obtained. The synthesized compounds were predicted in silico to exhibit biological activity with a high probability.

Bromination of N,N'-Bis(arylsulfonyl)-1,4-benzoquinonediimines and 1,4-Phenylenediamines

Depending on the solvent, molar reactant ratio, and other conditions, bromination of N,N'-bis(arylsulfonyl)-1,4-benzoquinonediimines and N,N'-bis(arylsulfonyl)-1,4-phenylenediamines yields 1,4-bis(arylsulfonylimino)-5,6-dibromo-2-cyclohexenes, N,N'-bis(ar

CHLORINATION OF N,N'-BISARYLSULFONYL-1,4-PHENYLENEDIAMINES AND N,N'-BISARYLSULFONYL-1,4-BENZOQUINONE DIIMINES

The chlorination of N,N'-bisarylsulfonyl-1,4-phenylenediamines leads to 1,4-bisarylsulfonylimino-2,3,5,5,6,6-hexachloro-2-cyclohexenes.Together with the chlorination products chloranil and/or 2,3,5,5,6,6-hexachloro-1,2-cyclohexene-1,4-dione were isolated as a result of the competing hydrolysis process.