5099-99-0Relevant academic research and scientific papers
Hydrogenation of BF2 complexes with 1,3-dicarbonyl ligands
?tefane, Bogdan,Polanc, Slovenko
body text, p. 2339 - 2343 (2009/07/18)
The catalytic hydrogenation (H2, Pd/C) of a set of BF2 complexes with a 1,3-dicarbonyl structural unit leading to monocarbonyl compounds has been studied. The transformation presented is general for the aryl-substituted derivatives and occurs under mild conditions (H2, 1 bar, 25 °C) in methanol or THF.
Direct Zn-diamine promoted reduction of C=O and C=N bonds by polymethylhydrosiloxane in methanol
Bette, Virginie,Mortreux, Andre,Lehmann, Christian W.,Carpentier, Jean-Francois
, p. 332 - 333 (2007/10/03)
Ketones and imines are chemoselectively reduced at room temperature in methanol to the corresponding alcohols and amines in high yields in a one-step procedure using polymethylhydrosiloxane (PMHS) and a simple zinc-diamine catalyst.
