50998-69-1Relevant academic research and scientific papers
A novel [2,3] intramolecular rearrangement of N-benzyl-O-allylhydroxylamines
Davies, Stephen G.,Jones, Simon,Sanz, Miguel A.,Teixeira, Fatima C.,Fox, John F.
, p. 2235 - 2236 (1998)
A novel [2,3]-sigmatropic rearrangement whereby N-benzyl-O-allylhydroxylamines undergo transformation to the corresponding N-allylhydroxylamines, which can subsequently be reduced to the corresponding allylamines, is described and evidence for the intramolecular nature of this process presented.
Selective Deprotection of N -Tosyl Alkoxyamines Using Bistrifluoromethane Sulfonimide: Formation of Oxime Ethers
Azizi, Mohamed Salah,Cossy, Janine
supporting information, p. 2417 - 2421 (2018/11/23)
The detosylation of N -tosyl alkoxyamines was realized by treatment with benzaldehyde and bistrifluoromethane sulfonimide as the catalyst to afford the corresponding oxime ethers. The reaction is chemoselective as N -tosyl amines are not deprotected. A me
The [2,3] sigmatropic rearrangement of N-benzyl-O-allylhydroxylamines
Davies, Stephen G.,Fox, John F.,Jones, Simon,Price, Anne J.,Sanz, Miguel A.,Sellers, Thomas G. R.,Smith, Andrew D.,Teixeira, Fatima C.
, p. 1757 - 1765 (2007/10/03)
The rearrangement of a range of N-benzyl-O-allylhydroxylamines to the corresponding N-allylhydroxylamines upon treatment with n-BuLi in THF, followed by reduction to the corresponding N-allylamines, is described. Mechanistic studies of the transformation are consistent with an intramolecular [2,3] sigmatropic rearrangement.
THE PREPARATION OF OXIME ETHERS UNDER PHASE TRANSFER CONDITION
Shinozaki, Hiraku,Yoshida, Noyuki,Tajima, Moritaka
, p. 869 - 870 (2007/10/02)
O-Butyloximes, O-allyloximes, O-2-chloroethyloximes, and O,O'-methylenedioximes were prepared from the corresponding oximes and halides under the phase transfer condition using sodium hydroxide and tetrabutylammonium bromide.
