51018-30-5Relevant academic research and scientific papers
1,2-Aminothioethers Derived from Ephedrine and Pseudoephedrine: Heterobidentate Ligands for the Palladium-Catalysed Asymmetric Allylic Substitution Reaction
Page, Philip C. Bulman,Heaney, Harry,Reignier, Serge,Rassias, Gerasimos A.
, p. 22 - 28 (2007/10/03)
Heterobidentate sulfide-tertiary amine ligands incorporating 1,2-aminothioethers derived from ephedrine and pseudoephedrine have been prepared and used successfully in the palladium-catalysed asymmetric allylic substitution reaction, giving ees of up to 89 percent. The stereoelectronic effects operating in the reactions are discussed.
