510774-06-8

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 98837-36-6 methyl 3-hydroxy-2-methylenebutyrate 
• 510774-05-7 2-[1-(tert-butyl-diphenyl-silanyloxy)-ethyl]-prop-2-en-1-ol 

Downstream Products

• 510774-04-6 (4-bromo-3-methylenepentyloxy)(tert-butyl)diphenylsilane 
• 916461-39-7 anti-(4R,5R,6E,8E)-1-(tert-butyldiphenylsilyloxy)-4,6,8,10,10-pentamethyl-3-methyleneundeca-6,8-dien-5-ol 
• 916461-60-4 (6E,8E)-1-(tert-butyldiphenylsilyloxy)-4,6,8,10,10-pentamethyl-3-methyleneundeca-6,8-dien-5-one 
• 510774-07-9 4-(tert-butyldiphenylsilyloxy)-3-methylenepentan-1-ol 

Relevant academic research and scientific papers

Studies towards total synthesis of antillatoxin: Indium-mediated allylation reaction of carbonyl compounds with secondary allylic bromide in aqueos media

We have established a new reaction condition for the indium-mediated allylation of an unreactive secondary allylic bromide with aldehydes in aqueous media to afford the corresponding homoallylic alcohols in high yields and syn diastereoselectivity. Furthe

Total synthesis of antillatoxin

The total synthesis of natural (4R,5R)-antillatoxin and its analog (4S,5S)-antillatoxin has been achieved; the optically pure key intermediates were prepared from indium mediated allylation of either primary or secondary allylic bromide with aldehyde in a