51114-10-4Relevant academic research and scientific papers
Direct heptafluoroisopropylation of arylboronic acids via hexafluoropropene (HFP)
Li, Yajun,Wang, Xiaojun,Guo, Yuwei,Zhu, Zhentong,Wu, Yongming,Gong, Yuefa
supporting information, p. 796 - 799 (2016/01/12)
A novel and straightforward strategy for heptafluoroisopropylation of arylboronic acids at room temperature has been developed. This method, directly using commercial available hexafluoropropene (HFP) as the starting material, provides a new way to synthesize a variety of synthetically useful heptafluoroisopropylated arenes.
A hexafluoropropylene directly to the aryl borate method of oxidation heptafluoro isopropylation
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Paragraph 0060-0066; 0147; 0148; 0149; 0150, (2016/10/20)
The invention relates to a method for directly oxidizing arylboronic acid into heptafluoroisopropyl by utilizing hexafluoropropylene. The method comprises the following steps that silver fluoride is used as a fluorine source, under the effect of copper salt, the hexafluoropropylene and the arylboronic acid can be converted into a series of compounds containing heptafluoroisopropyl in organic solvents at the room temperature, and the reaction is also applicable to alkenylboronic acids. The method has the advantage that a series of compounds containing the heptafluoroisopropyl are synthesized through one-step reaction at high selectivity.
PERFLUOROISOPROPYBENZENE DERIVATIVE
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, (2008/06/13)
Perfluoroisopropylbenzene derivatives of the general formula (I) or salts thereof, useful as intermediates or raw materials in the synthesis of various industrial materials including agricultural chemicals, drugs and surfactants, wherein X1 is
PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS BETWEEN ALLYL, VINYL OR ARYL HALIDE AND PERFLUOROALKYL IODIDE WITH ZINC AND ULTRASONIC IRRADIATION
Kitazume, Tomoya,Ishikawa, Nobuo
, p. 137 - 140 (2007/10/02)
The reactions of perfluoroalkyl iodides with allyl, vinyl or aryl halides with ultrasonically dispersed zinc in the presence of palladium catalyst proceeded smoothly to give the corresponding allyl, vinyl or aryl perfluoroalkylides in a good yield.
