51119-86-9Relevant academic research and scientific papers
Ruthenium olefin metathesis catalysts containing six-membered sulfone and sulfonamide chelating rings
Szadkowska, Anna,Zukowska, Karolina,Pazio, Aleksandra E.,Wozniak, Krzysztof,Kadyrov, Renat,Grela, Karol
experimental part, p. 1130 - 1138 (2011/04/26)
The preparation and X-ray structure characterization of new olefin metathesis initiators containing sulfone- and sulfonamide-substituted benzylidene ligands are described. We observed that these catalysts exhibit Ru???O(SO)R interactions, forming six-memb
Intramolecular Nucleophilic Catalysis by the Neighboring Hydroxyl Group in Acid- and Base-Catalyzed Hydrolysis of Aromatic Sulfonamides and Sultones. Mechanism of Intramolecular Nucleophilic Substitution at Sulfonyl Sulfur
Wagenaar,Anno,Engberts, Jan B.F.N.
, p. 768 - 772 (2007/10/02)
This paper reports kinetic data illustrating the effectiveness of the Thorpe-Ingold gem-dialkyl effect in speeding the intramolecular nucleophilic catalyzed conversion of o-(1-hydroxyalkyl)-N,N-dimethylbenzenesulfonamides 1 into the corresponding sultones
