511544-01-7Relevant academic research and scientific papers
Spacer-mediated synthesis of contra-thermodynamic spiroacetals: Stereoselective synthesis of C2-symmetric difructose dianhydrides
Rubio, Enrique M.,Garcia-Moreno, M. Isabel,Balbuena, Patricia,Lahoz, Fernando J.,Alvarez, Eleuterio,Mellet, Carmen Ortiz,Garcia Fernandez, Jose M.
, p. 2257 - 2266 (2007/10/03)
The xylylene moiety (ortho, meta, and para) was employed as a rigid tether in the spacer-mediated synthesis of difructose dianhydrides (DFAs), a unique class of bis-spiroacetal derivatives present in food products. The synthetic methodology exploits the s
Carbohydrate-derived spiroketals: Stereoselective synthesis of di-D-fructose dianhydrides via intramolecular aglycon delivery
Rubio, Enrique M.,Ortiz Mellet, Carmen,Garcia Fernandez, Jose M.
, p. 873 - 876 (2007/10/03)
(Matrix presented) A one-pot synthesis of C2-symmetric di-D-fructose dianhydrides having the 1,6,9,13-tetraoxadispiro [4.2.4.2]tetradecane skeleton has been accomplished via intramolecular aglycon delivery from (6 → 6) xylylene-tethered fructof
