51202-31-4Relevant academic research and scientific papers
Synthesis of 5-Amino-4-cyanopyrazole from 1,1-Dicyanoalkenes and Elemental Dinitrogen using a Tungsten Complex
Colquhoun, Howard M.,Crease, Allan E.,Taylor, Stephen A.
, p. 1158 - 1159 (2007/10/02)
Electrochemical reduction of the dinitrogen-derived dicyanovinyl hydrazido(2-) complex + - in tetrahydrofuran yields 5-amino-4-cyanopyrazole in up to 50percent yield; when carried out under N2, the metal-containing product of reduction is + -, but under CO the dicarbonyl complex W(dppe)2(CO)2 is formed.
