512169-15-2

Upstream product

• 598-21-0 2-Bromoacetyl bromide 
• 512169-13-0 O-benzyl-N-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)hydroxylamine 
• 647-42-7 1H,1H,2H,2H-tridecafluoro-n-octanol 
• 78522-69-7 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl trifluoromethanesulfonate 

Downstream Products

• 512169-35-6 N-benzyloxy-2-(2-ethoxy-ethoxy)-N-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-acetamide 
• 512169-24-3 N-benzyloxy-2-pentyloxy-N-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-acetamide 
• 512169-27-6 N-benzyloxy-2-(4-chloro-butoxy)-N-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-acetamide 
• 512169-29-8 N-benzyloxy-2-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-undecyloxy)-N-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-acetamide 

Relevant academic research and scientific papers

Convenient synthetic methods for the preparation of N-fluoroalkylhydroxamic acids

Polyhydroxamate chelators containing fluoro substituents are of interest as potential extractants for actinides in separations involving supercritical carbon dioxide. In this context, we have developed three new reagents 1, 2, and 3, that allow the efficient incorporation of an N-fluoroalkyl hydroxamate moiety onto a variety of substrates using acylation, alkylation, and Michael addition strategies.