51246-92-5Relevant academic research and scientific papers
Branching of poly(ADP-ribose): Synthesis of the Core Motif
Kistemaker, Hans A. V.,Overkleeft, Herman S.,Van Der Marel, Gijsbert A.,Filippov, Dmitri V.
, p. 4328 - 4331 (2015)
The synthesis of the core motif of branched poly(adenosine diphosphate ribose) (poly(ADPr)) is described, and structural analysis reasserted the proposed stereochemistry for branching. For the synthesis, a ribose trisaccharide was first constructed with only α-O-glycosidic linkages. Finally, the adenine nucleobase was introduced via a Vorbrüggen-type glycosylation reaction. The orthogonality of the selected protecting groups was demonstrated, allowing for the construction of branched poly(ADPr) oligomers in the near future.
Photolytische Decarbonylierung von Anhydrozucker-Ulosen zur Synthese von 1,5-Anhydro-β-D-lyxo- und -ribofuranosen sowie 2,6-Anhydro-β-D-psicofuranosen
Heyns, Kurt,Neste, Helmut-Rainer,Thiem, Joachim
, p. 891 - 908 (2007/10/02)
By photochemical decarbonylation of the 1,6-anhydro-2- (1) and -4-uloses (3) with D-lyxo configuration stereoselective ring contractions yield the 1,5-anhydro-β-D-lyxofuranose derivative 2.Via corresponding transformations the benzylidene derivative 9 is
