51262-06-7

Upstream product

• 40167-15-5 N-(phenylsulphinyl)phthalimide 
• 2216-51-5 (-)-menthol 
• 98-09-9 benzenesulfonyl chloride 
• 34513-32-1 O-(1R,2S,5R)-(-)-menthyl (S)-benzenesulfinate 
• 4972-29-6 benzenesulphinyl chloride 
• 15356-60-2 (1S,2R,5S)-(+)-menthol 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 1601-94-1 (R)-1-(1-phenylethylsulfonyl)benzene 
• 22852-28-4 (((R_S,R_C)-1-phenylethyl)sulfinyl)benzene 
• 99493-60-4 (SS,1S,2R)-N-(1-methoxy-1-phenyl-2-propyl)benzenesulfinamide 
• 89299-86-5 (+)-(R)_S-phenyl vinyl sulfoxide 
• 51207-25-1 (R)-ethyl phenyl sulfoxide 

Relevant academic research and scientific papers

Organic reactions under solid-state conditions

Manipulatively simple and rapid methods are described for the synthesis of: chiral sulfinate esters from sulfonyl chlorides and sufonic acids; aldehydes and ketones from oximes, alcohols, hydrozones; sulfoxides from sulfides; and disulfides from thiols. The chemical yields are good to excellent and diastereoselectivity is high.

Highly diastereoselective synthesis and easy method for synthesis of optically active sulfinate esters from aromatic disulfides

One-step synthesis of chiral aromatic sulfinate esters 2 from aromatic disulfides 1 using lead tetraacetate is reported. The yields are good to excellent and diastereoselectivity is high.

Oligomerization of Vinyl Monomers. 17. Stereoselective Methylation of 1-Lithio-1,3-bis(phenylsulfinyl)butane. Kinetic vs. Thermodynamic Control in the Formation of Diastereomeric Ion Paors

The addition of (R) or (R,S)-vinyl phenyl sulfoxide (3) to (R)- or (R,S)-1-lithio-(phenylsulfinyl)ethane (2) was carried out in THF at -78 deg C, and the adduct anion 4 was protonated or methylated to produce 1,3-bis(phenylsulfinyl)butane (6) or 2,4-bis(p