512782-93-3

Upstream product

• 98-88-4 benzoyl chloride 
• 512783-16-3 C₂₇H₃₆O₇ 
• 64180-78-5 4-bromopent-4-en-1-ol 
• 92975-38-7 4-bromo-4-pentenoic acid tert-butyl ester 
• 512782-99-9 5-(tert-butyldimethylsilyloxy)-2-methylenepentanal 
• 512783-10-7 C₂₇H₃₆O₆ 
• 512783-01-6 (1S,2S,3R,4S)-2-[(Z)-6-(tert-Butyl-dimethyl-silanyloxy)-3-methylene-hex-1-enyl]-3-(4-methoxy-benzyloxy)-7,7-dimethyl-1-vinyl-bicyclo[2.2.1]heptan-2-ol 
• 512783-00-5 tert-butyl-(6-iodo-4-methylene-hex-5-enyloxy)-dimethyl-silane 
• 350715-38-7 (1S,2R,4S,5S,9R,11S,12S)-5,11,12-Trihydroxy-2-(4-methoxy-benzyloxy)-4,15,15-trimethyl-8-methylene-tricyclo[10.2.1.0^4,9]pentadecan-3-one 
• 350715-39-8 (1S,4R,8S,9S,10R,11R,12S)-1,8,10-Trihydroxy-11-(4-methoxy-benzyloxy)-9,15,15-trimethyl-5-methylene-tricyclo[10.2.1.0^4,9]pentadecan-2-one 
• 350715-36-5 4-[(1S,5S,7S,8R,10R,11S)-10-(4-Methoxy-benzyloxy)-8,14,14-trimethyl-3,9-dioxo-2,4-dioxa-tricyclo[9.2.1.0^1,5]tetradec-7-yl]-pent-4-enal 
• 120001-35-6 ((4-bromopent-4-en-1-yl)oxy)(tert-butyl)dimethylsilane 

Relevant academic research and scientific papers

Effect of 9,10-cyclic acetal stereochemistry on feasible operation of the α-ketol rearrangement in highly functionalized paclitaxel (Taxol) precursors

The convergent, stereocontrolled synthesis of enantiopure stereoisomeric 9,10-cyclic acetals, whose designed role was to serve as potential precursors to Taxol, is reported. These advanced intermediates are multiply functionalized and carry a bridgehead α