512791-23-0Relevant articles and documents
Synthetic studies on Diels-Alder adducts: Intramolecular interactions between two functions
Gomes Constantino, Mauricio,De Souza, Altamiro Xavier,Da Silva, Gil Valdo José
, p. 475 - 486 (2007/10/03)
In this paper we describe the synthesis of a ?,?-unsaturated aldehyde from a bicyclic Diels-Alder adduct, to be used in future electrocyclic reaction studies. A number of reactions produced undesired materials resulting from the interaction between functions, forcing the use of partial protection to accomplish a synthesis that would be otherwise straightforward. Suggestions to account for the results are given.
Novel Route to Some Biologically Important Compounds Starting with a Common Chiral, Bicyclic, Fused Lactone: Enantioselective Synthesis of (-)-Boschnialactone and Two Antithrombotics
Arai, Yoshitsugu,Kawanami, Saburo,Koizumi, Toru
, p. 2969 - 2976 (2007/10/02)
Three biologically important compounds, (-)-boschnialactone and the antithrombotics (+)- and (-)-(5Z)-6-hept-5-en-2-endo- and exo-yl>hex-5-enoic acid have been synthesized starting from a common
Enantioselective Synthesis of (-)-Boschnialactone
Arai, Yoshitsugu,Kawanami, Saburo,Koizumi, Toru
, p. 1585 - 1586 (2007/10/02)
An enantioselective synthesis of (-)-boschnialactone was accomplished starting from a chiral fused bicycloheptane lactone readily available via an asymmetric Diels-Alder reaction.