512809-21-1

Basic information

• Product Name: 2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-
• CAS NO: 512809-21-1
• Molecular Formula: C13H14O3
• Molecular Weight: 218.252
• Mol File: 512809-21-1.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-(512809-21-1)
• EPA Substance Registry System: 2H-Pyran-3(6H)-one, 2-methyl-6-(phenylmethoxy)-, (2S,6R)-(512809-21-1)

Safety Data

• Hazardous Substances Data: 512809-21-1(Hazardous Substances Data)

Upstream product

• 865484-73-7 tert-butyl ((2S,6S)-6-methyl-5-oxo-5,6-dihydro-2H-pyran-2-yl) carbonate 
• 100-51-6 benzyl alcohol 
• 4208-64-4 (S)-1-(2-furanyl)ethanol 
• 41728-14-7 6-hydroxy-2-methyl-2H-pyran-3(6H)-one 
• 1192-62-7 1-(2-furyl)-1-ethanone 
• 4208-64-4 1-(2-furyl)ethanol 
• 34819-86-8 3,4-di-O-acetyl-6-deoxy-L-glucal 
• 76404-29-0 phenylmethyl 4-O-acetyl-2,3,6-trideoxy-α-L-erythro-hex-2-enopyranoside 
• 76404-30-3 Benzyl-2,3,6-tridesoxy-α-L-erythro-hex-2-enopyranosid 

Downstream Products

• 1174754-24-5 (1R,2R,4S,6S)-2-(benzyloxy)-4-methyl-3,7-dioxabicyclo[4.1.0]-heptan-5-one 
• 1174754-25-6 (2R,3R,4S,5R,6S)-2-(benzyloxy)-6-methyltetrahydro-2H-pyran-3,4,5-triol 
• 1174754-26-7 (2R,3R,5R,6S)-2-(benzyloxy)-6-methyltetrahydro-2H-pyran-3,5-diol 
• 71731-74-3 (2R,3S,4R,5S,6S)-2-(benzyloxy)-6-methyltetrahydro-2H-pyran-3,4,5-triol 
• 1335126-18-5 (2R,3S,4S,5R,6S)-2-(benzyloxy)-6-methyltetrahydro-2H-pyran-3,4,5-triol 
• 1334606-85-7 (2R,3R,6S)-2-(benzyloxy)-6-methyl-3,6-dihydro-2H-pyran-3-ol 
• 1334606-94-8 (2R,3R,6S)-2-(benzyloxy)-6-methyltetrahydro-2H-pyran-3-ol 
• 727414-86-0 (2R,6S)-2-(benzyloxy)-6-methyl-2H-pyran-3(6H)-one 
• 1334607-00-9 (2R,6S)-2-(benzyloxy)-6-methyl-3,6-dihydro-2H-pyran-3-ol 
• 1334607-07-6 (2R,6S)-2-(benzyloxy)-6-methyl-3,6-dihydro-2H-pyran-3-yl pivalate 
• 1334607-11-2 (((2R,6S)-2-(benzyloxy)-6-methyl-3,6-dihydro-2H-pyran-3-yl)oxy)(tert-butyl)dimethylsilane 
• 1334607-15-6 (2R,3S,6S)-2-(benzyloxy)-6-methyltetrahydro-2H-pyran-3-ol 
• 1334607-28-1 (2R,3S,4R,5S,6S)-2-(benzyloxy)-4,5-dihydroxy-6-methyltetrahydro-2H-pyran-3-yl pivalate 
• 1334607-25-8 (2R,3S,4S,5R,6S)-2-(benzyloxy)-4,5-dihydroxy-6-methyltetrahydro-2H-pyran-3-yl pivalate 

Relevant articles and documents

Catalytic Asymmetric Synthesis of All Possible Stereoisomers of 2,3,4,6-Tetradeoxy-4-Aminohexopyranosides

We recently developed a divergent strategy for the synthesis of all eight possible 2,3,6-trideoxyhexopyranosides with three stereogenic centers. However, the diastereoselectivity for one of the three stereogenic centers was low and it was not controlled b

Chiral Catalyst-Directed Dynamic Kinetic Diastereoselective Acylation of Lactols for de Novo Synthesis of Carbohydrate

The control of the stereochemistry at the anomeric position is still one of the major challenges of synthetic carbohydrate chemistry. We have developed a new strategy consisting of a chiral catalyst-directed acylation followed by a palladium-catalyzed gly

Application of the Wharton rearrangement for the de novo synthesis of pyranosides with ido, manno, and colito stereochemistry

A de novo asymmetric synthesis of α-ido-pyranosides, as well as several deoxy and amino variants, has been achieved. The procedure involves a palladium(0)-catalyzed glycosylation in combination with a Wharton rearrangement/epoxide-opening reaction sequence to access sugars with ido, manno, and colito stereochemistry as well as several azido analogues. A de novo asymmetric synthesis of α-ido-pyranosides, as well as several deoxy and amino variants, has been achieved. The procedure involves a palladium(0)- catalyzed glycosylation in combination with a Wharton rearrangement/epoxide- opening reaction sequence to access sugars with ido, manno, and colito stereochemistry as well as several azido analogues. Copyright