512827-89-3Relevant academic research and scientific papers
Diastereoselective nitrilimine cycloaddition to the C=N bond of enantiopure 1,4-benzodiazepinones
Molteni, Giorgio,Broggini, Gianluigi,Pilati, Tullio
, p. 2491 - 2495 (2007/10/03)
Enantiopure 1,4-benzodiazepin-4-one 1 and 1,4-benzodiazepin-6-ones 2 were reacted with hydrazonoyl chloride 8 in the presence of various basic agents. The diastereoselective 1,3-dipolar cycloaddition between the C=N double bond of 1 or 2 and the nitrilimi
