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Tris(dibenzylideneacetone)dipalladium
Cas No: 51364-51-3
No Data 1 Gram 100 Metric Ton/Month Yurui(Shanghai)Chemical Co.,Ltd Contact Supplier
Tris(dibenzylideneacetone)dipalladium
Cas No: 51364-51-3
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Hangzhou Dayangchem Co., Ltd. Contact Supplier
Tris(dibenzylideneacetone)dipalladium(0)
Cas No: 51364-51-3
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 100 Metric Ton/Week Hebei yanxi chemical co.,LTD. Contact Supplier
fresh Tris(Dibenzylideneacetone)Dipalladium in stock with best price
Cas No: 51364-51-3
USD $ 1.0-1.0 / Metric Ton 1 Metric Ton 1000 Metric Ton/Day Scale Chemical Corporation Contact Supplier
Tris(dibenzylideneacetone)dipalladium
Cas No: 51364-51-3
No Data 1 Kilogram 20 Metric Ton/Month Henan Allgreen Chemical Co.,Ltd Contact Supplier
High quality Tris(Dibenzylideneacetone)Dipalladium supplier in China
Cas No: 51364-51-3
No Data No Data No Data Simagchem Corporation Contact Supplier
Tris(dibenzylideneacetone)dipalladium
Cas No: 51364-51-3
USD $ 2900.0-3000.0 / Kilogram 1 Kilogram 10 Kilogram/Day Henan DaKen Chemical CO.,LTD. Contact Supplier
Tris(dibenzylideneacetone)dipalladium
Cas No: 51364-51-3
No Data No Data Metric Ton/Day Beijing Greenchem Technology Co.,Ltd.(Qingdao Greenchem international Trading Co.,Ltd) Contact Supplier
Tris(dibenzylideneacetone)dipalladium
Cas No: 51364-51-3
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 3500 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier
Tris(dibenzylideneacetone)dipalladium 51364-51-3
Cas No: 51364-51-3
No Data 100 Kilogram 300 Kilogram/Month HENAN SUNLAKE ENTERPRISE CORPORATION Contact Supplier

51364-51-3 Usage

Chemical Properties

dark purple solid

Description

Tris(dibenzylideneacetone) dipalladium (Tris DBA) is used as catalyst for a wide variety of Pd catalyzed reactions including Suzuki coupling, Heck coupling, Negishi coupling, Carroll reaarangement, Trost asymmetric allylic alkylation, Buchwald-Hartwig amination of acryl halides, fluorination of allylic chlorides, arylation of ketones, carbonylation of 1,1-dichloro-1-alkenes, ß-arylation of carboxylic esters, and conversion of aryl and vinyl triflates to aryl and vinyl halides. It is also involved in the synthesis of azepane. Tris DBA is also a novel inhibitor of N-myristoyltransferase-1 with significant antitumor activity.

Reactions

1. Catalyst precursor for conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics.
2. Catalyst for the synthesis of epoxides.
3. Catalytic asymmetric allylic and homoallylic diamination of terminal olefins.
4. Site-selective benzylic sp3 palladium-catalyzed direct arylation.
5. Palladium-catalyzed one-pot synthesis of tricyclic indolines.
6. Active catalyst for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles.
7. Catalyst in combination with BINAP for the asymmetric Heck Arylation of olefins.
8. Precursor for palladium-catalyzed carbon-nitrigen bond formation.
9. Catalyst for α-arylation of ketones,
10. Cross-coupling of aryl halides with aryl boronic acids.

Uses

suzuki reaction

Uses

A cycloaddition catalyst.

References

  1. https://en.wikipedia.org/wiki/Tris(dibenzylideneacetone)dipalladium(0)
  2. http://www.sigmaaldrich.com
  3. https://www.alfa.com
  4. https://pubchem.ncbi.nlm.nih.gov
  5. S. S. Bhandarkar, J. Bromberg, C. Carrillo, P. Selvakumar, R. K. Sharma, B. N. Perry, B. Govindarajan, L. Fried, A. Sohn, K. Reddy and J. L. Arbiser, Tris (Dibenzylideneacetone) Dipalladium, a N-Myristoyltransferase-1 Inhibitor, Is Effective against Melanoma Growth In vitro and In vivo, Clinical Cancer Research, 2008, vol. 18, 5743-5748
InChI:InChI=1/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b13-11+,14-12+;2*13-11-,14-12+;;

51364-51-3 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (685135)  Tris[dibenzylideneacetone]dipalladium(0),ChemDosetablets  Loading: 0.5μmol per tablet (1μmol Pd per tablet) 51364-51-3 685135-100TAB 6,382.35CNY Detail
Aldrich (685135)  Tris[dibenzylideneacetone]dipalladium(0),ChemDosetablets  Loading: 0.5μmol per tablet (1μmol Pd per tablet) 51364-51-3 685135-10TAB 1,071.72CNY Detail
Alfa Aesar (12760)  Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min    51364-51-3 25g 8441.0CNY Detail
Alfa Aesar (12760)  Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min    51364-51-3 5g 2221.0CNY Detail
Alfa Aesar (12760)  Tris(dibenzylideneacetone)dipalladium(0), Pd 21.5% min    51364-51-3 1g 853.0CNY Detail
TCI America (T2184)  Tris(dibenzylideneacetone)dipalladium(0)  >75.0%(T) 51364-51-3 5g 1,390.00CNY Detail
TCI America (T2184)  Tris(dibenzylideneacetone)dipalladium(0)  >75.0%(T) 51364-51-3 1g 450.00CNY Detail

51364-51-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name Tris(dibenzylideneacetone)dipalladium

1.2 Other means of identification

Product number -
Other names Pd2(dibenzylideneacetone)3

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:51364-51-3 SDS

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