51414-47-2Relevant articles and documents
Efficient 1,3 ester shift in α-disubstituted β-ketoester enolates. Remarkable influence of the metal counterion on the rate of reaction
Habi,Gravel
, p. 4315 - 4318 (1994)
The efficient and rapid α to γ rearrangement of the carbalkoxy group in α-disubstituted β-ketoesters is reported. The reaction proceeds at room temperature and in high yields when performed under naked anion conditions. A crossover experiment using approp