51425-32-2Relevant academic research and scientific papers
Interaction of pyridineplatinum(II) complexes with alkyl sulfoxides
De Vekki
, p. 1238 - 1241 (2009/02/03)
Interaction of pyridineplatinum(II) complexes with dimethyl sulfoxide and diethyl sulfoxide is studied by NMR spectroscopy. The interaction products are pyridinesulfoxide and bissulfoxide platinum(II) complexes. Cis-trans isomerization of the products is
Reactivity of geometric isomers of (-)-dichloropyridine(methyl-para-tolylsulfoxide)platinum(II) by optical rotatory dispersion
De Vekki,Spevak,Skvortsov
, p. 579 - 584 (2008/10/08)
The reactions of the optically active geometric isomers of the platinum(II) complex (-)-[Pt(Me-p-TolSO)(Py)Cl2] with several nucleophilic reagents (Py, Ph3PS, Ph3P, Ph3As, and Me2SO) were studied by optical rotatory dispersion, IR spectroscopy, and 1H and 31P NMR spectroscopy. A mechanism for the reaction is proposed.
