51433-21-7

Basic information

• Product Name: Methyl 2-O,3-O-dimethyl-α-D-glucopyranosiduronic acid methyl ester
• Synonyms: Methyl 2-O,3-O-dimethyl-α-D-glucopyranosiduronic acid methyl ester
• CAS NO: 51433-21-7
• Molecular Formula: C₁₀H₁₈O₇
• Molecular Weight: 250.24572
• Mol File: 51433-21-7.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Methyl 2-O,3-O-dimethyl-α-D-glucopyranosiduronic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2-O,3-O-dimethyl-α-D-glucopyranosiduronic acid methyl ester(51433-21-7)
• EPA Substance Registry System: Methyl 2-O,3-O-dimethyl-α-D-glucopyranosiduronic acid methyl ester(51433-21-7)

Safety Data

• Hazardous Substances Data: 51433-21-7(Hazardous Substances Data)

Usage

General Description

Methyl 2-O,3-O-dimethyl-α-D-glucopyranosiduronic acid methyl ester, also known as methyl glucopyranosiduronic acid, is a chemical compound that is an ester derivative of glucopyranosiduronic acid. It is a methyl ester of a sugar acid, and is often used in chemical and pharmaceutical research as a precursor for the synthesis of various carbohydrate derivatives. Methyl 2-O,3-O-dimethyl-α-D-glucopyranosiduronic acid methyl ester is an important intermediate in the production of glycosidic compounds and can be used as a building block for the synthesis of various natural products and pharmaceuticals. Its structure and properties make it a valuable tool in the study of carbohydrate chemistry and drug development.

Upstream product

• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 3013-58-9 methyl 4,6-O-benzylidene-2,3-di-O-methyl-α,D-glucopyranoside 
• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 907574-05-4 1,2,3-tri-O-methyl-α-D-glucopyranuronic acid 
• 67-56-1 methanol 
• 3013-58-9 methyl 4,6-O-benzylidene-2,3-di-O-methyl-α-D-glucopyranoside 
• 74-88-4 methyl iodide 
• 186581-53-3 diazomethane 
• 18486-51-6 1-O-methyl-α-D-glucopyranuronic acid methyl ester 
• 10227-29-9 methyl 2,3-di-O-methyl-α-D-glucopyranoside 

Downstream Products

• 63167-89-5 O¹,O²,O³-trimethyl-O⁴-(4-nitro-benzoyl)-α-D-glucopyranuronic acid methyl ester 

Relevant articles and documents

Differential reactivity of α- and β-anomers of glycosyl acceptors in glycosylations. A remote consequence of the endo-anomeric effect?

(equation presented) When phenyl tri-O-benzyl-1-thio-β-D-galactopyranosiduronic acid esters were coupled with a 1/1 mixture of a and β 2,3 di-O-protected D-galactopyranosiduronic acid esters, the β-anomer proved to be more reactive. Data from theoretical

Process of preparation of L-iduronic acid comprising a decarboxylation/intramolecular cyclisation tandem reaction

The present invention relates to a process of preparation of L-iduronic acid and derivatives comprising a decarboxylation/intramolecular cyclisation tandem reaction. The present invention also relates to the intermediates of the process, as well as their use as intermediates in the preparation of Idraparinux.

Synthesis pathway to carbohydrate-derived salicylidene hydrazides as ligands for oxovanadium complexes

Salicylidene hydrazides represent important ligands forming oxovanadium complexes. Carbohydrate-derived chiral salicylidene hydrazides as ligands for metal ion complexation were synthesized for the first time. The pathway of the mild and selective synthesis starts from commercial saccharides like methyl-α-d-glucopyranoside and methyl-α-d-mannopyranoside. All synthesized carbohydrate-derived salicylidene hydrazides are able to form oxovanadium complexes. The mononuclear structure proposed for the complex of 1,2,3,4-tetra-O-methyl-α-d-glucopyranuronic acid salicylidene hydrazide is consistent with the analytical data (NMR, IR and MS).