514806-50-9

Basic information

• Product Name: (4-azido-2-phenyl-thiazol-5-yl)-methanol
• Synonyms: (4-azido-2-phenyl-thiazol-5-yl)-methanol
• CAS NO: 514806-50-9
• Molecular Weight: 232.266
• Mol File: 514806-50-9.mol

Chemical Properties

• CAS DataBase Reference: (4-azido-2-phenyl-thiazol-5-yl)-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (4-azido-2-phenyl-thiazol-5-yl)-methanol(514806-50-9)
• EPA Substance Registry System: (4-azido-2-phenyl-thiazol-5-yl)-methanol(514806-50-9)

Safety Data

• Hazardous Substances Data: 514806-50-9(Hazardous Substances Data)

Upstream product

• 115437-26-8 4-azido-5-formyl-2-phenylthiazole 

Downstream Products

• 514806-53-2 4-azido-2-phenyl-5-(phthalimidomethyl)thiazole 
• 514806-51-0 4-azido-5-bromomethyl-2-phenyl-thiazole 

Relevant articles and documents

New applications of the imine-ketenimine intramolecular [2+2] cycloaddition reaction: Highly stereocontrolled synthesis of azeto[1,2-a]pyrimidines

Imino-ketenimines 7, in which the reactive functionalities are linked by an allylic tether connecting the imino and ketenimino nitrogen atoms, undergo a formal intramolecular [2+2] cycloaddition to yield azeto[1,2-a]pyrimidines 8. When enantiotopic ketenimine and imine fragments are combined, the resulting azeto[1,2-a]pyrimidines 8e-i contain two stereogenic carbon atoms C-6 and C-7, and the cycloaddition takes place with complete diastereoselectivity in favor of the cis diastereoisomers. This methodology has also been applied to the preparation of some azeto[1,2-a][1,3]thiazolo[4,5-d]pyrimidines 16, representative examples of a new fused heterocyclic system. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2002.