51487-40-2Relevant academic research and scientific papers
Mechanism and selectivity of radical alkylation of 3,4-Dichloro-2,5- dihydrofuran-2,5-dione
Trukhin,Messorosh,Karavan,Eliseenkov
, p. 801 - 811 (2007)
The mechanism of radical alkylation of 3,4-dichloro-2,5-dihydrofuran-2,5- dione with cyclohexane and 2,3-dimethylbutane follows an addition-elimination pattern with reversible formation of alkyl radicals. The proposed kinetic scheme takes into account the
A facile synthesis of alkyl substituted maleic anhydrides: radical approach
Messorosh, Artyom V.,Trukhin, Alexey V.,Eliseenkov, Evgenii V.
, p. 10849 - 10852 (2008/12/23)
Synthetic background for the preparation of alkyl substituted maleic anhydrides and maleimides based on radical alkylation of 2,3-dichloromaleic anhydride (maleimide) by hydrocarbons was developed. The best conditions for the selective synthesis of 2-alkyl-3-chloro- and unsymmetrically substituted dialkylmaleic anhydrides were elaborated.
New free-radical chain processes involving substitution of vinyl and aryl chlorides by alkanes, alkenes, esters and ethers
Araneo, Silvia,Arrigoni, Riccardo,Bjorsvik, Hans-Rene,Fontana, Francesca,Liguori, Lucia,Minisci, Francesco,Recupero, Francesco
, p. 6897 - 6900 (2007/10/03)
New free-radical substitutions of vinyl and aryl chlorides by alkanes, alkenes, ethers and esters are described. The free-radical chains are rationalized on the basis of the known kinetics of the elementary steps involved.
