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SOLVOLYSIS OF gem-DIHALOGENOCYCLOPROPANES IN THE PRESENCE OF SILVER SALTS
Molchanov, A. P.,Kostikov, R. R.
, p. 429 - 435 (2007/10/02)
The methanolysis and acetolysis of substituted gem-dibromo- and gem-bromofluorocyclopropanes in the presence of silver salts lead to the products from opening of the three-membered ring.Their ratio is determined by the charge distribution in the intermediate cation.When heated the obtained thermodynamically less stable isomers isomerize to the more stable isomers.
