51529-72-7

Upstream product

• 495-69-2 Hippuric Acid 
• 105-07-7 4-cyanobenzaldehyde 
• 98-88-4 benzoyl chloride 
• 874-89-5 4-Cyanobenzyl alcohol 

Downstream Products

• 90290-91-8 N-[(Z)-2-(4-Cyano-phenyl)-1-(morpholine-4-carbonyl)-vinyl]-benzamide 
• 90290-90-7 N-[(Z)-2-(4-Cyano-phenyl)-1-(4-methyl-piperidine-1-carbonyl)-vinyl]-benzamide 
• 90290-89-4 N-[(Z)-2-(4-Cyano-phenyl)-1-cyclohexylcarbamoyl-vinyl]-benzamide 
• 90291-22-8 N-[(Z)-1-(Morpholine-4-carbonyl)-2-(4-thiocarbamoyl-phenyl)-vinyl]-benzamide 
• 90291-11-5 N-[(Z)-2-(4-Carbamimidoyl-phenyl)-1-diethylcarbamoyl-vinyl]-benzamide; hydrochloride 
• 90291-09-1 N-[(Z)-2-(4-Carbamimidoyl-phenyl)-1-(pyrrolidine-1-carbonyl)-vinyl]-benzamide; hydrochloride 
• 90291-02-4 4-((Z)-2-Benzoylamino-2-diethylcarbamoyl-vinyl)-benzimidic acid methyl ester; hydrochloride 
• 90291-10-4 N-[(Z)-1-Butylcarbamoyl-2-(4-carbamimidoyl-phenyl)-vinyl]-benzamide; hydrochloride 
• 90291-00-2 4-((Z)-2-Benzoylamino-3-oxo-3-pyrrolidin-1-yl-propenyl)-benzimidic acid methyl ester; hydrochloride 
• 90291-08-0 N-[(Z)-2-(4-Carbamimidoyl-phenyl)-1-(piperidine-1-carbonyl)-vinyl]-benzamide; hydrochloride 
• 90291-14-8 N-[(Z)-2-(4-Carbamimidoyl-phenyl)-1-(morpholine-4-carbonyl)-vinyl]-benzamide; hydriodide 
• 90291-01-3 4-((Z)-2-Benzoylamino-2-butylcarbamoyl-vinyl)-benzimidic acid methyl ester; hydrochloride 
• 90290-99-6 4-((Z)-2-Benzoylamino-3-oxo-3-piperidin-1-yl-propenyl)-benzimidic acid methyl ester; hydrochloride 
• 90291-12-6 N-[(Z)-2-(4-Carbamimidoyl-phenyl)-1-cyclohexylcarbamoyl-vinyl]-benzamide; hydrochloride 

Relevant academic research and scientific papers

Chemoselective Transfer Hydrogenation of Enamides Using Ru Pincer Complexes for the Synthesis of α-Amino Acids

The chemoselective reduction of enamides to α-amino acids with iPrOH and EtOH as H-donors and solvents catalyzed by Ru pincer complexes is demonstrated. A range of α-amino acids is synthesized in good to excellent yields. Applications, large scale, and a one-pot experiment are also reported. Finally, deuterium-labeling experiments show high regioselectivity between the α-and β-positions of the alkene unit.

Synthesis and spectroscopic analysis of benzylidene imidazolone linked to P-porphyrins through axial ligand

Tetraphenylporphyrinatophosphorus(V) complexes (1) comprising two axially linked benzylidene imidazolone (Biz) moieties, which are chromophores of the green fluorescent protein, were prepared. In medical applications such as photodynamic therapy, the P-po

Benzylidene-oxazolones as photoswitches: Photochemistry and theoretical calculations

The photophysics and photochemistry of a family of compounds proposed as efficient molecular photoswitches is presented. The effect of different light sources, substituents and solvents in the photostationary state has been explored. A detailed mechanisti

Construction of adjacent spiro-quaternary and tertiary stereocenters through phosphine-catalyzed asymmetric [3+2] annulation of allenoates with alkylidene azlactones

A novel axially chiral spiro-phosphine-catalyzed highly regio-, diastereo- and enantioselective [3+2] cycloaddition of alkylidene azlactones with various allenic esters has been developed, affording the corresponding functionalized spirocyclic products in

Novel and chemoselective one-pot synthesis of 4-arylidene-2-phenyl-5(4H)- oxazolones starting from benzyl alcohols promoted by [(C14H 24N4)2W10O32]-[bmim] NO3

A new and practical promoter system for one-pot, efficient, chemoselective synthesis of 4-arylidene-2-phenyl-5(4H)-oxazolones using [(C14H 24N4)2W10O32]-[bmim] NO3 under solvent-free conditions is described. The present work opens up a new and ecofriendly synthetic route to Erlenmeyer-Ploechl adducts from primary benzyl alcohols in a one-pot operation. Graphical abstract: [Figure not available: see fulltext.]

2W10O32. 2H2O: A novel and powerful catalyst for the synthesis of 4-arylidene-2-phenyl-5(4)-oxazolones under ultrasonic condition

Di[1,6-bis(3-methylimidazolium-1-yl)hexane] decatungstate dihydrate ([C6(MIm)2]2W10O32. 2H2O) as a new family of polyoxometalate-based dicationic ionic liquids (POM-DIL) is synthesized and employed as a novel and powerful heterogeneous catalyst in the synthesis of 4-arylidene-2-phenyl-5(4)-oxazolones (azlactones) under ultrasound-assisted solvent-free condition. On the basis of the results, the products were obtained in excellent yields under mild condition. Utilization of easy work-up and purification make it very interesting from an economic perspective. Moreover, a recycling study confirmed that the catalyst can be reused multiple times without significant loss of its activity.

Oxazolinone compounds useful as intermediates for the preparation of insecticidal and acaricidal agents

The present invention relates to novel oxazolinone compounds and a method for the preparation thereof. These compounds are useful intermediates in the preparation of cinnamamide insecticides and acaricides.

New oxazolinone compounds useful as intermediates for the preparation of insecticidal and acaracidal cinnamide compounds

The present invention relates to novel cinna-mamide compounds and oxazolinone compounds and processes for the preparation thereof. The compounds of the invention are useful for controlling insects and acarina and the oxazolinone also are useful intermedia

Insecticidal cinnamamide compounds and method for controlling insects therewith

The present invention relates to novel cinnamamide compounds and a process for the preparation thereof. The compounds of the invention are useful for controlling insects and acarina.

INVESTIGATION OF AZLACTONES AND AZLACTAMS BY IR SPECTROSCOPY

The IR spectra of a number of azlactones and their structural analogs, viz., azlactams, in solutions in carbon tetrachloride and in chloroform and in the solid phase were obtained.The character of the interaction of the carbonyl group of the heteroring with substituents with different electronic natures has a substantial effect on the frequencies of the stretching vibrations of the carbonyl group and the azomethine and ethylene bonds.The carbonyl frequencies were subjected to correlation analysis, and high conductivity of the electronic effects of substituents in the 2-phenyl-4-arylideneoxazol-5-one series was ascertained.