516508-03-5

Basic information

• Product Name: (3S,4S,5S)-3-{[(tert-butyl)dimethylsilyl]oxy}-5-(hydroxymethyl)-4-(2,2,2-trifluoroacetamido)cyclohexanone
• Synonyms: (3S,4S,5S)-3-{[(tert-butyl)dimethylsilyl]oxy}-5-(hydroxymethyl)-4-(2,2,2-trifluoroacetamido)cyclohexanone
• CAS NO: 516508-03-5
• Molecular Weight: 369.456
• Mol File: 516508-03-5.mol

Chemical Properties

• CAS DataBase Reference: (3S,4S,5S)-3-{[(tert-butyl)dimethylsilyl]oxy}-5-(hydroxymethyl)-4-(2,2,2-trifluoroacetamido)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S,5S)-3-{[(tert-butyl)dimethylsilyl]oxy}-5-(hydroxymethyl)-4-(2,2,2-trifluoroacetamido)cyclohexanone(516508-03-5)
• EPA Substance Registry System: (3S,4S,5S)-3-{[(tert-butyl)dimethylsilyl]oxy}-5-(hydroxymethyl)-4-(2,2,2-trifluoroacetamido)cyclohexanone(516508-03-5)

Safety Data

• Hazardous Substances Data: 516508-03-5(Hazardous Substances Data)

Upstream product

• 516508-02-4 (1R,6S,7S,8S)-8-{[(tert-butyl)dimethylsilyl]oxy}-1-{[(1'R,2'S)-2'-phenylcyclohexyl]oxy}-2,4-dioxa-3-azatricyclo[4.3.1.0^3,7]decane 
• 516508-01-3 (4S,6R)-4-{[(tert-butyl)dimethylsilyl]oxy}-5,6-dihydro-6-{[(1'R,2'S)-2'-phenylcyclohexyl]oxy}-6-(prop-2''-enyl)-4H-1,2-oxazine 2 oxide 
• 516508-00-2 (1E)-1-{[(tert-butyl)dimethylsilyl]oxy}-2-nitroethene 
• 383-63-1 ethyl trifluoroacetate, 

Relevant articles and documents

Tandem inter [4+2]/intra [3+2] cycloadditions of nitroalkenes. Application to the synthesis of aminocarbasugars

The tandem inter [4+2]/intra [3+2] cycloaddition of nitroalkenes in the bridged mode was applied to the stereoselective synthesis of β-D-4-amino-2,4-dideoxycarbagulose, a representative aminocarbasugar. The synthesis required only five steps from known ma