51666-97-8Relevant articles and documents
Synthesis of α-Fluoromethyl Ketones via Allene Epoxides
Kabat, Marek M.
, p. 435 - 440 (1989)
α-Fluoromethyl ketones are formed via the reaction of allene epoxides with tetrabutylammonium fluoride trihydrate (TBAF*3H2O) in THF.
SILICON IN ORGANIC SYNTHESIS-17 CYCLOPENTANNULATION BY THERMOLYSIS OF (1-TRIMETHYLSILYLCYCLOPROPYL)ETHYLENES-THE 1-TRIMETHYLSILYLCYCLOPROPYL ANION
Paquette, Leo A.,Wells, Gregory J.,Horn, Keith A.,Yan, Tu-Hsin
, p. 913 - 924 (2007/10/02)
Several alternatives for preparing (1-trimethylsilylcyclopropyl)ethylenes have been examined.Although 1-lithio-1-(trimethylsilyl)ethylene does add satisfactorily to carbonyl compounds and the subsequent Simmons-Smith cyclopropanation provides the desired