82084-04-6Relevant academic research and scientific papers
SILICON IN ORGANIC SYNTHESIS-17 CYCLOPENTANNULATION BY THERMOLYSIS OF (1-TRIMETHYLSILYLCYCLOPROPYL)ETHYLENES-THE 1-TRIMETHYLSILYLCYCLOPROPYL ANION
Paquette, Leo A.,Wells, Gregory J.,Horn, Keith A.,Yan, Tu-Hsin
, p. 913 - 924 (2007/10/02)
Several alternatives for preparing (1-trimethylsilylcyclopropyl)ethylenes have been examined.Although 1-lithio-1-(trimethylsilyl)ethylene does add satisfactorily to carbonyl compounds and the subsequent Simmons-Smith cyclopropanation provides the desired
SILICON IN ORGANIC SYNTHESIS. 13. THE 1-TRIMETHYLSILYLCYCLOPROPYL ANION AND ITS FORMAL EQUIVALENT
Paquette, Leo A.,Horn, Keith A.,Wells, Gregory J.
, p. 259 - 262 (2007/10/02)
Reaction of lithio 1-trimethylsilylcyclopropane or its formal equivalent with carbonyl compounds leads to carbinols which dehydrate without rearrangement.Other attempts to induce ring expansion of the silicon substituted three-membered ring by i
